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        Designing and modification of bismuth oxyhalides BiOX (X = Cl, Br and I) photocatalysts for improved photocatalytic performance

        Irshad Ahmad,Shazia Shukrullah,Muhammad Yasin Naz,Sami Ullah,Mohammed Ali Assiri 한국공업화학회 2022 Journal of Industrial and Engineering Chemistry Vol.105 No.-

        Photocatalysis has emerged as a promising technology for solving global environmental and energy challenges. The selectivity of low-cost, non-toxic and thermochemically stable materials for photocatalyticapplications is crucial to meet the industrial standards. Despite of owing unique layered structure, distinctelectronic band structure and tunable optical properties, the bismuth oxyhalides BiOX (X = Cl, Brand I) photocatalytic materials suffer from rapid recombination of charge carriers and limited lightabsorption issues. These limitations restrict the photocatalytic efficiency and industrial applications ofBiOX materials. The focus of this critical review is to discuss recent developments in the design and modificationof existing and new BiOX materials for getting optimum photocatalytic response from thesematerials. The key elements of the review are BiOX synthesis methods, BiOX driven water splitting, singleand double stage hydrogen evolution systems, degradation of organic pollutants and trends of boostingthe photocatalytic efficiency of the BiOX materials. Finally, this insight discusses the existing issues andfuture perspectives of BiOX photocatalysts.

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