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- 저자 : Rohan Weerasooriya (검색결과 2 건)
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Ce3+ triggers fenton-like processes in neutral solutions for effective catechol degradation
Xing Chen,Xu Liu,Hai-Bo Wang,Kang-Ping Cui,Rohan Weerasooriya,Shi-Long He,Guang-Hong Li,Jun Pan,Kai Zhou 대한환경공학회 2022 Environmental Engineering Research Vol.27 No.1
Classical Fenton and Fenton-like processes destruct organic pollutants in water non-selectively to complete mineralization. However, the usage of classical Fenton or Fenton-like processes is often limited due to the narrow operational pH window, sludge accumulation, inefficient H₂O₂ and efficiency decline. To overcome these constraints, in this study, we used a homogeneous Fe<SUP>3+</SUP>-Ce<SUP>3+</SUP>-H₂O₂ Fenton-like process to degrade catechol at different experimental conditions. At pH 7, almost 97% of 10 mM catechol can be destructed within 60 min while the degradation by Classical Fenton or Fe<SUP>3+</SUP>-H₂O₂ Fenton-like process only 36.2% and 23.7%. The resultant solution after the degradation contains only traces of cerium ions. The sludge created by the process was extensively characterized by FTIR and XPS spectroscopy to elucidate the fate of cerium ions. Electron spin resonance (ESR) data confirmed •OH as the major free radical in Fe<SUP>3+</SUP>-Ce<SUP>3+</SUP>-H₂O₂ process. Our Fenton-like process widens the optimal pH values to neutral condition.
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Huilai Liu,Minshu Cui,Yao Liu,Defeng Kong,Zhihao Li,Rohan Weerasooriya,Xing Chen 한국공업화학회 2023 Journal of Industrial and Engineering Chemistry Vol.125 No.-
Sulfamethoxazole (SMX) is a widely used antibiotic drug in medical applications resulting in its ubiquityin water and wastewater. Most of the treatment processes are inefficient in destroying SMX in water. Theheterogeneous electro-Fenton (EF)process shows promise in the non-selective degradation of antibioticdrugs in water and wastewater. Fe2O3/MXene-x (x is the ferric ion loading) was fabricated on 2DMXene carriers by hydrothermal method. The Fe2O3/MXene-x substrates were characterized by electronmicroscopic, X-ray, and molecular spectroscopic methods. Degradative products of SMX were identifiedby free radical quenching and LC-MS measurements. Electron micrographs show that Fe2O3 particulatesare uniformly distributed on MXene nanosheets. Fe2O3/MXene-x coated graphite was used as a cathodewith titanium anode for in situ generation of H2O2 required to produce free radicals (e.g. OH and O2 – ) todestroy SMX. Three possible SMX degradation routes by the electro-Fenton process were proposed. SMXand intermediates are eventually mineralized as CO2 and H2O. The new electrocatalyst shows reducedmetal ions leaching and good stability in repeated use cycles. This work offers a new electro-Fentonmethod to destroy antibiotic drugs in water and wastewater.
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