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Antibacterial Chitosan Hybrid Films with N-halamine-Functionalized Graphene Oxide
Mengdi Zuo,Nengyu Pan,Tung-Shi Huang,Ick Soo Kim,Xuehong Ren 성균관대학교(자연과학캠퍼스) 성균나노과학기술원 2020 NANO Vol.15 No.03
Graphene, a single layer of two-dimensional carbon material, has attracted much attention due to its excellent comprehensive properties including high mechanical strength, antibacterial property, excellent thermal and electrical conductivities, high specific surface area, impermeability, etc. In this study, 3-epoxypropyl-5,5-dimethylhydantoin (GH), as a precursor of N-halamine, was synthesized and attached onto graphene oxide (GO) for enhanced antibacterial activity. The synthesized GO–GH was characterized by Fourier transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM), thermogravimetric analysis (TGA) and X-ray photoelectron spectroscopy (XPS). After chlorination treatment by house-hold bleach solution, the chlorinated graphene oxide-3-epoxypropyl-5,5-dimethyl hydantoin (GO–GH–Cl) possessed great antibacterial efficacy. The synthesized GO–GH–Cl was added to chitosan (CS) solution to produce GO–GH–Cl/CS hybrid films via a solution casting method. The as-prepared antimicrobial hybrid fllms showed excellent antibacterial activity and could kill 100% of S. aureus and 100% of E. coli O157:H7 within 10min and 30 min of contact time, respectively.
Tong Mu,Nengyu Pan,Yingfeng Wang,Xuehong Ren,Tung-Shi Huang 한국섬유공학회 2018 Fibers and polymers Vol.19 No.11
In this study, we synthesized a novel N-halamine precursor, sulfuric acid mono-[2-(4-[4-chloro-6-(2-[4,4- dimethyl-2,5-dioxo-imidazolidin-1-yl]-ethylamino)-[1,3,5]triazin-2-ylamino]-benzenesulfonyl)-ethyl] ester sodium (TB), which contains two reactive groups of monochloro triazine reactive groups and bis-sulphatoethylsolphone reactive groups. The structure of TB is similar to iso-bifunctional group reactive dyes and could be coated on cotton fabrics by covalent bonds through a reactive dyeing process. The cotton coated with TB was characterized by FTIR and SEM. After chlorination, the treated cotton fabrics showed excellent antibacterial efficacy and inactivated all inoculated S. aureus (ATCC 6538) and E. coli O157: H7 (ATCC 43895) within 1 min of contact. Over 85 % of tensile strength retained both in warp and weft directions after treatment and chlorination. Almost 80 % of active chlorine can be regained by treating with household bleach after extensive washing and long time storage.