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        Pressure-assisted combustion synthesis of red-emitting SrIn₂O₄: Eu3+ phosphor powders for applications in solid state white lamps

        C.E. Rodríguez-García,N. Perea-López,S.P. DenBaars,G.A. Hirata 한양대학교 세라믹연구소 2008 Journal of Ceramic Processing Research Vol.9 No.5

        Red-emitting phosphor powders of SrIn2O4 activated with Eu3+ ions were synthesized by a high pressure assisted combustion method. X-ray diffraction analysis of the crystalline properties of these powders revealed single phase SrIn2O4 for Eu concentrations up to 4 atomic % of Eu. The photo and cathodoluminescence emission spectra of SrIn2O4: Eu3+ powder shows bright red emission mainly caused by the 5D0→7F2 intra-shell transition of Eu3+. Furthermore, photoluminescence excitation (PLE) spectroscopy revealed that an efficient energy transfer from the SrIn2O4 host lattice onto the Eu ions is accomplished in addition to the excitation band peaked at λ = 396 nm that directly excites the Eu ions, making this material an excellent candidate for applications in solid state white-emitting lamps. Red-emitting phosphor powders of SrIn2O4 activated with Eu3+ ions were synthesized by a high pressure assisted combustion method. X-ray diffraction analysis of the crystalline properties of these powders revealed single phase SrIn2O4 for Eu concentrations up to 4 atomic % of Eu. The photo and cathodoluminescence emission spectra of SrIn2O4: Eu3+ powder shows bright red emission mainly caused by the 5D0→7F2 intra-shell transition of Eu3+. Furthermore, photoluminescence excitation (PLE) spectroscopy revealed that an efficient energy transfer from the SrIn2O4 host lattice onto the Eu ions is accomplished in addition to the excitation band peaked at λ = 396 nm that directly excites the Eu ions, making this material an excellent candidate for applications in solid state white-emitting lamps.

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