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        Fabrication of Aligned PI/GO Nanofibers for Battery Separators

        Qiong Tian,Qiuhong Liu,Kedong Song,Yufan Mei,Jinfeng Peng,Jinfeng Peng,Ji Zhou,Yanhuai Ding 한국섬유공학회 2021 Fibers and polymers Vol.22 No.1

        Highly aligned polyimide/graphene oxide (PI/GO) nanofibers were fabricated by using the electrospinning method. As a separator for Li-ion batteries, the PI/GO nanofibers show excellent thermal stability, good wettability toward organicliquid electrolytes and superior electrochemical performance compared to raw PI and commercial battery separators. TheGO nanosheets not only greatly enhance the mechanical strength of the PI matrix, but also increase the resistance to Lidendrites.

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        Preparation and property evaluation of a temperature-resistant Zr-crosslinked fracturing fluid

        Ming Zhou,Jinfeng Zhang,Zhonghua Zuo,Mao Liao,Peng’ao Peng 한국공업화학회 2021 Journal of Industrial and Engineering Chemistry Vol.96 No.-

        Compared with the traditional water-based fracturingfluid thickener guanidine gum, the price ofsynthetic polymer is relatively low, and the temperature resistance, shear resistance and viscoelasticityof the formed fracturingfluid are better. Therefore, the fracturingfluid formed by the crosslinking ofHPAM and organic metal crosslinker will become one of the hot spots in the research of water-basedfracturingfluid. In this paper, zirconium oxychloride, acetic acid and triethanolamine were used as rawmaterials to prepare organic Zr-crosslinked agent. The polymer gel was formed by crosslinking theorganic Zr-crosslinked agent with the acrylamide copolymer KY-5S solution, and the viscosity of the gelwith different concentrations was investigated. The performance of the fracturingfluid was evaluatedthrough laboratory experiments. The results showed that the viscosity of the fracturingfluid remainedabove 100 mPa s at the shear rate of 170 s 1 and after 2 h of shear at 140 C. When the temperature was20 C, the shear stress was 0.1 Pa, and the frequency f varied from 0.1 to 10 Hz, the elastic modulus offracturingfluid was at least 11.6 Pa, and the viscous modulus was at least 8.54 Pa. At the temperature of90 C, when the addition of glue breaker was 0.01 wt%, the longest breaking time was 3 h, and themaximum viscosity of breaking liquid was 4.05 mPa s. The damage rate of core permeability of gluebreaker was about 13%. When the temperature was 25 C and the shear rate was 0–170 s-1, the viscosity offracturingfluid remained above 200 mPa s.

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        Mechanism and process for the extraction of lithium from the high magnesium brine with N,N-bis(2-ethylhexyl)-2-methoxyacetamide in kerosene and FeCl3

        Lianmin Ji,Licheng Zhang,Dong Shi,Xiaowu Peng,Jinfeng Li,Yuze zhang,Taoshan Xu,Lijuan Liao 한국공업화학회 2022 Journal of Industrial and Engineering Chemistry Vol.113 No.-

        The degradation of TBP has become a stumbling block to the industrial continuous production of lithiumchloride extraction from brines with high Mg/Li ratio by solvent extraction. To develop a more stable andmore efficient extraction system, a novel amide system, containing newly synthesized extractant N,N-bis(2-ethylhexyl)-2-methoxyacetamide (NBEHMOA), FeCl3 6H2O and sulfonated kerosene, was proposed inthis work. Compared with TBP and N523, NBEHMOA extracted Li+ and H+ in the sequence of TBP ˃NBEHMOA ˃ N523 and N523 ˃ TBP ˃ NBEHMOA respectively. The solution containing 5.5 mol/L LiCland 0.5 mol/L HCl was used as the eluent in the scrubbing process. A Li+ extraction efficiency of 96.7%and 22.31 g/L Li+ in the stripping solution were achieved by the whole process with counter-currenttwelve stages. The extraction mechanism investigated via FT-IR spectroscopy illustrated that the metalions Fe3+ and Li+ were mainly coordinated by the carbonyl C = O in NBEHMOA. This novel amide systemcan successfully achieve the cascade extraction effect for lithium, Li/Mg separation and avoid the generationof phase interface objects through counter-current extraction of lithium from brine at a lower acidity. This work provided a novel extraction system to recover lithium from the higher magnesium/lithiumratio brines.

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