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      • Synthesis of a Novel Ce-bpdc for the Effective Removal of Fluoride from Aqueous Solution

        Zhao, Changqing,Cui, Yanwei,Fang, Fang,Ryu, Si Ok,Huang, Jiarui Hindawi Limited 2017 Advances in condensed matter physics Vol.2017 No.-

        <P>Ce-1,1′-biphenyl-4,4′-dicarboxylic acid (Ce-bpdc), a novel type of metal organic framework, was synthesized and applied to remove excessive fluoride from water. The structure and morphology of Ce-bpdc were measured by X-ray diffraction, scanning electron microscopy, Fourier transform infrared spectroscopy, and X-ray photoelectron spectroscopy. The effects, such as saturated adsorption capacity, <SUP><SUB>HCO3</SUB>-</SUP>, and pH, were investigated. The optimal pH value for fluoride adsorption was the range from 5 to 6. The coexisting bicarbonate anions have a little influence on fluoride removal. The fluoride adsorption over the Ce-bpdc adsorbent could reach its equilibrium in about 20 min. The Ce-bpdc coordination complex exhibited high binding capacity for fluoride ions. The maximum adsorption capacity calculated from Langmuir model was high up to 45.5 mg/g at 298 K (pH = 7.0) and the removal efficiency was greater than 80%. In order to investigate the mechanism of fluoride removal, various adsorption isotherms such as Langmuir and Freundlich were fitted. The experimental data revealed that the Langmuir isotherm gave a more satisfactory fit for fluoride removal. Finally, the tested results of ground water samples from three places, Yuefang, Jiangji, and Sanyi which exhibited high removal efficiency, also demonstrate the potential utility of the Ce-bpdc as an effective adsorbent.</P>

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        Modified Model Free Adaptive Control for a Class of Nonlinear Systems with Multi-threshold Quantized Observations

        Xiangquan Li,Zhengguang Xu,Yanrong Lu,Jiarui Cui,Lixin Zhang 제어·로봇·시스템학회 2021 International Journal of Control, Automation, and Vol.19 No.10

        This paper addresses a pattern-moving-based modified model free adaptive control (PMFAC) scheme and illustrates the convergence of its tracking error for a class of nonlinear systems with unknown model and multi-threshold quantized observations. The basic idea is to consider the system’s quantization error as an external disturbance and an improved performance index function of control law is proposed from the perspective of twoplayer zero-sum game (TP-ZSG) based on the existed MFAC algorithms. The PMFAC scheme is established which mainly includes an improved tracking control law and a pseudo-partial derivative (PPD) estimation algorithm. Under certain conditions, the bounded convergence of system tracking error and the stability of PMFAC system with quantization errors can be guaranteed. The theoretical results are demonstrated by two numerical examples.

      • KCI등재

        Pattern-moving-based Robust Model-free Adaptive Control for a Class of Nonlinear Systems with Disturbance and Data Dropout

        Xiangquan Li,Zhengguang Xu,Cheng Han,Jiarui Cui 제어·로봇·시스템학회 2022 International Journal of Control, Automation, and Vol.20 No.11

        The ability to deal with the system disturbance and/or data dropout is often referred to as the robustness of model-free or data-driven control theory. This paper addresses a novel pattern-moving-based partial-form dynamic linearization intermittent model-free adaptive control scheme for a class of nonlinear discrete-time systems with disturbance and random measurement data dropout. Furthermore, the bounded convergence of the tracking error of the closed-loop system is proved by the statistical approach with contraction mapping principle. The basic idea is to consider the pattern-moving-based partial-form dynamic linearization model-free adaptive control method under the condition of missing data which may be caused by network failure, failing sensor or actuator. The designed scheme mainly includes an improved intermittent tracking control law, an intermittent classification-metric bias estimation algorithm and a modified intermittent pseudo gradient vector estimation algorithm. The bounded convergence and effectiveness of the proposed scheme are demonstrated by both the rigorous mathematical inference and two numerical examples.

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