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Sorption of Pd on illite, MX-80 bentonite and shale in Na-Ca-Cl solutions
Goguen, Jared,Walker, Andrew,Racette, Joshua,Riddoch, Justin,Nagasaki, Shinya Korean Nuclear Society 2021 Nuclear Engineering and Technology Vol.53 No.3
This paper examines sorption of Pd(II) onto illite, MX-80 bentonite, and Queenston shale in Na-Ca-Cl solutions of varying ionic strength (IS) from 0.01 to 6.0 mol/L (M) and pH<sub>c</sub> ranging from 3 to 9 under atmospheric conditions. A 2-site protolysis non-electrostatic surface complexation and cation exchange model was applied to the Pd sorption onto illite and MX-80 using PHREEQC, and the model results were compared to the experimental ones obtained in this work. Surface complexation and cation exchange constants were estimated for both illite and MX-80 through the optimization process to bring the predicted distribution coefficients from the model into alignment with the experimentally derived values. These optimized surface complexation constants were compared to existing linear free energy relationships (LFER).
Shinya Nagasaki,Takumi Saito,Satoru Tsushima,Jared Goguen,Tammy Yang 한국원자력학회 2017 Nuclear Engineering and Technology Vol.49 No.8
The interaction of NpO+ 2 with Cl- was studied using visibleenear-infrared spectroscopy in NaCl-Ca- Cl2-NaClO4, NaCl-NaClO4, and CaCl2-NaClO4 solutions with ionic strength (I) of 6M. The spectra of NpO+2 around 980 nm varied with Cl- concentration in the NaCl-CaCl2-NaClO4 and NaCl-NaClO4 solutions at [Cle] ≥ 3.5M, but not in the CaCl2-NaClO4 solution. Assuming the 1:1 interaction between NpOþ+ and Cl-, the apparent equilibrium constants at I = 6M were evaluated. The presence of Ca2+ was found to destabilize overall interaction between NpOþ 2 and Cle. The observations were consistent with the density functional theory calculation.