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Wear properties of ECAP-processed ultrafine grained Al-Cu alloys
Abd El Aal, M.I.,El Mahallawy, N.,Shehata, F.A.,Abd El Hameed, M.,Yoon, E.Y.,Kim, H.S. Elsevier Sequoia 2010 Materials science & engineering. properties, micro Vol.527 No.16
The wear properties of equal channel angular pressing (ECAP) Al-2, 3 and 5%Cu alloys under dry sliding conditions using different sliding distances and loads were investigated by pin-on-disc dry sliding wear tests. The wear mass loss decreased remarkably as the number of ECAP passes and Cu content increased, being affected more by the sliding distance than by the applied load under the experimental conditions. The wear mechanism was observed to be adhesive and delamination initially, and an abrasive mechanism also appeared as the sliding distance increased. The analysis of the wear surface indicates a transfer of Fe from the rotating disc to the Al-Cu alloy pin with increases in the sliding distance, the applied load, the number of passes and the copper content.
Recycling of AlSi8Cu3 alloy chips via high pressure torsion
Abd El Aal, M.I.,Yoo Yoon, E.,Seop Kim, H. Elsevier Sequoia 2013 Materials science & engineering. properties, micro Vol.560 No.-
In this paper, AlSi8Cu3 alloy chips were consolidated via HPT at an applied pressure 8GPa for 10 revolutions at room temperature. The microstructure and hardness of the HPT consolidated chips were investigated and compared with those of the HPT processed solid AlSi8Cu3 alloy samples and cold compacted chip samples. The HPT process successfully resulted in fully densified bulk samples with a higher microhardness due to the finer Al matrix grains and Si particles sizes with more grain boundaries with high angles and more homogeneous deformation than those in the HPT processed solid AlSi8Cu3 alloy samples due to the higher imposed total strain.
Adsorption of Phenols onto Chemically-Activated Carbons Developed from Wild Cherry Stones
Alaya, M.N.,Youssef, A.M.,Karman, M.,Abd El-Aal, H.E. Korean Carbon Society 2006 Carbon Letters Vol.7 No.3
Phosphoric acid-activated carbon WP's and zinc chloride-activated carbons WZ's were developed from wild cherry stones. The textural properties of the activated carbons were determined from nitrogen adsorption data at 77 K and the chemistry of the carbon surface, i.e. the surface carbon-oxygen groups (type and amount) was determined from the base and acid neutralization capacities (Boehm method). The adsorption of phenol, p-nitrophenol, p-chlorophenol, dinitrophenol and dichlorophenol was followed at 298 K. The activated carbons obtained were characterized by high surface area and large pore volumes as well as by high surface concentration of C-O groups. The investigated carbons exhibited high adsorption capacities towards phenols with these capacities increased with the increase of molecular weight and the decrease of the solubility of phenol in water. However, no general relationship could be observed between the adsorption capacities of carbons and any of their textural parameters or their surface chemistry. This may be attributed to the many factors controlling phenol adsorption and the different types and mechanisms of adsorption involved.
Adsorption of Phenols onto Chemically-Activated Carbons Developed from Wild Cherry Stones
M.N. Alaya,A.M. Youssef,M. Karman,H.E. Abd El-Aal 한국탄소학회 2006 Carbon Letters Vol.7 No.3
Phosphoric acid-activated carbon WP's and zinc chloride-activated carbons WZ's were developed from wild cherry stones. The textural properties of the activated carbons were determined from nitrogen adsorption data at 77 K and the chemistry of the carbon surface, i.e. the surface carbon-oxygen groups (type and amount) was determined from the base and acid neutralization capacities (Boehm method). The adsorption of phenol, p-nitrophenol, p-chlorophenol, dinitrophenol and dichlorophenol was followed at 298 K. The activated carbons obtained were characterized by high surface area and large pore volumes as well as by high surface concentration of C-O groups. The investigated carbons exhibited high adsorption capacities towards phenols with these capacities increased with the increase of molecular weight and the decrease of the solubility of phenol in water. However, no general relationship could be observed between the adsorption capacities of carbons and any of their textural parameters or their surface chemistry. This may be attributed to the many factors controlling phenol adsorption and the different types and mechanisms of adsorption involved.
M.N. Alaya,A.M. Youssef,M. Karman,H.E Abd El-Aal 한국탄소학회 2006 Carbon Letters Vol.7 No.1
Activated carbons were obtained by activating wild cherry stones with different concentrations of phosphoric acid or zinc chloride at different temperatures. The adsorption of N2 at 77 K and of CO2 at 273 K was followed and the data were analyzes by considering different adsorption models. The activated carbons obtained measured high surface area with the most of the surface in all samples located in micropores. Fair agreement was found between the nitrogen surface areas calculated from the BET-, t-, α- and DR- methods, although the first three are based on surface coverage whereas the latter is based on micropore filling. The carbon dioxide surface areas calculated by the DA equation were smaller than the comparable nitrogen areas. This was ascribed to domination of surface coverage mechanism, the absence of activated diffusion process. Based on this explanation the CO2-surface areas as calculated by DA equation should be taken with great reservation.
Alaya, M.N.,Youssef, A.M.,Karman, M.,Abd El-Aal, H.E Korean Carbon Society 2006 Carbon Letters Vol.7 No.1
Activated carbons were obtained by activating wild cherry stones with different concentrations of phosphoric acid or zinc chloride at different temperatures. The adsorption of $N_2$ at 77 K and of $CO_2$ at 273 K was followed and the data were analyzes by considering different adsorption models. The activated carbons obtained measured high surface area with the most of the surface in all samples located in micropores. Fair agreement was found between the nitrogen surface areas calculated from the BET-, t-, ${\alpha}$- and DR- methods, although the first three are based on surface coverage whereas the latter is based on micropore filling. The carbon dioxide surface areas calculated by the DA equation were smaller than the comparable nitrogen areas. This was ascribed to domination of surface coverage mechanism, the absence of activated diffusion process. Based on this explanation the $CO_2$-surface areas as calculated by DA equation should be taken with great reservation.