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Selective hydrogenation of furfural to cyclopentanone over Cu-Ni-Al hydrotalcite-based catalysts
Hongyan Zhu,Guomin Xiao,Minghao Zhou,Zuo Zeng,Rui Xiao 한국화학공학회 2014 Korean Journal of Chemical Engineering Vol.31 No.4
A series of Cu-Ni-Al hydrotalcites derived oxides with a (Cu+Ni)/Al mole ratio of 3 with varied Cu/Nimole ratio (from 0.017 to 0.5, with a Cu ratio of 0.0125 to 0.25) were prepared by co-precipitation method, then appliedto the hydrogenation of furfural in aqueous. Their catalytic performance for liquid phase hydrogenation of furfural toprepare cyclopentanone was described in detail, considering reaction temperature, catalyst composition, reaction timeand so on. The yield of cyclopentanone was influenced by the mole ratio of Cu-Ni-Al based heterogeneous catalystand depended on the reaction conditions. The yield of cyclopentanone was up to 95.8% when the reaction was carriedout under 413 K with H2 pressure of 40 bar for 8 h. The catalysts were characterized by X-ray powder diffraction (XRD),scanning electron microscope (SEM) and H2 temperature-programmed reduction (H2-TPR).
Lufei Tian,Minghao Zhou,Xiaomei Pan,Guomin Xiao,Yunqing Liu 한국화학공학회 2015 Korean Journal of Chemical Engineering Vol.32 No.8
Supercritical (Sc)-CO2 extraction was adopted to extract ginkgolic (G.) acids from ginkgo biloba exopleura. Response surface optimization was employed to maximize extraction recovery of G. acids from ginkgo biloba exopleura. The effects of pressure, temperature, CO2 mass flow rate, dosage of entrainer and extraction static-dynamic time on the yield of G. acids were investigated in detail, and the central composite design was used to maximize the extraction recovery of G. acids. The amounts of G. acids were analyzed by HPLC with the mixture of methanol and acetic acid solution as the mobile phase. The optimal process parameters for sc-CO2 extraction were determined to be: 31.3MPa extraction pressure, 46.1 oC extraction temperature and 11.1 g min−1 CO2 flow rate, 30mL ethanol entrainer, 1 h extraction static time and 2 h dynamic time. Under the conditions of optical extraction process, the average G. acids extraction rate was 74mg g−1.
Yuanfeng Wu,Xianghai Song,Shuai Li,Jiahui Zhang,Xinghui Yang,Pengxin Shen,Lijing Gao,Ruiping Wei,Jin Zhang,Guomin Xiao 한국공업화학회 2018 Journal of Industrial and Engineering Chemistry Vol.58 No.-
[(CH3)2NH2][M3(BTC)(HCOO)4(H2O)].H2O (M–BTC, M = Mn, Ni, Co) were prepared under hydrothermal conditions and used as highly efficient catalysts for cycloaddition of CO2 with epichlorohydrin (ECH). The microstructure and physicochemical properties of the compounds were determined by PXRD, FT-IR, XPS, N2-adsorption, TG–DSC, NH3–TPD and CO2–TPD. 98.01% conversion of ECH and 96.05% selectivity to chloropropene carbonate was obtained over the Mn–BTC under the optimized reaction conditions (105 °C, 3.0 MPa, 9 h, 1.5 wt.% of ECH). Besides, the recyclability result exhibited the Mn–BTC compound can be utilized as least three times with a slight reduction in its catalytic ability. In addition, cycloaddition of CO2 with other epoxides and DFT calculation were also performed. The result exhibited the yield followed the order: ECH > 1, 2-epoxybutane > propene oxide > Allyl glycidyl ether, which was mainly determined by the energy of reaction.
Weihao Zhu,Yuanfeng Wu,Guiyun Yi,Xiaoxiao Su,Qiangsheng Pan,Shengbin Shi,Olayinka Oderinde,Guomin Xiao,Chuanxiang Zhang,Yulong Zhang 한국공업화학회 2023 Journal of Industrial and Engineering Chemistry Vol.119 No.-
The present work is aimed at studying the synergistic catalysis of the bimetal ZIFs containing Co and Znmetal ions prepared by solvothermal method in the degradation of organic pollutants under ambientconditions. The bimetal mixed ZIFs were further characterized by some techniques such as XRD, SEM,TG-DTG, XPS, UV–vis, ESR, and N2-adsorption. Interestingly, the sample prepared with equal metal ions(1Zn:1Co) showed the highest catalytic performance for methylene blue (MB) degradation (94.10 %). Thismay be associated with the interaction between cobalt and zinc within the adjacent lattice, which makethe MB molecule to be easily adsorbed and degraded on empty electron orbit. Furthermore, the highestdegradation of MB was achieved with 98.83 % under the optimized conditions (catalyst weight of 50 mg,pH of 5, 3 h, 30 C). Besides, the various substrates such as methyl orange, indole, rofloxacin, methyl blue,and tetracycline were also investigated under the same conditions. Additionally, the DFT calculationresults suggested the more orbital distribution (LUMO, HOMO) of ZIF(1Zn:1Co) can result to more electronsbeing easily captured, and generate more radicals via electron transfer. Finally, the photocatalyticdegradation of MB is consistent with the first law of kinetics, and the activation energy is 26.797 KJ/molin the presence of ZIF(1Zn:1Co).