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      • 폴리우레탄 섬유의 染色機構에 關한 硏究

        金公朱,朴炳基,姜濚義 全北大學校 1980 論文集 Vol.22 No.-

        Spandex is man-made elastomer fiber. Chemically, polyurethane is produced by interaction of Glycol and Diisocyanate. From a physical point of view, these Spandex fibers owe their elasticity to the same thermodynamics as rubber, therefore, the high degree of fabric stretch availability permits its use in a wide range of textile fabrics. Particular interests are to improve the dyeing properties and to find out the dyeing mechanism. So, it is the purpose of this paper to present technology which will permit these yarn to be dyed with selected dyes and to describe the dyeing mechanism.

      • Saccharin의 展望性있는 化學的 製法과 副産物의 利用에 關한 硏究

        柳珙植 群山大學校 1983 論文集 Vol.6 No.-

        It seems very likely that the consumption of saccharin will be increased, according to the increasing national income and the variety of processed foodstuffs, with demand of carolieless foodstuffs for the prevention of supernutrition and diseases of adult people. Therefore all the nations in the world have been concentrated on developing artificial sweetstuffs substituting sugar for. As a result of it, the manufacturing process in the past was the one which used to solve O-toluene Sulfon Amid with 30% Sodium Hydroxide; this time the method is the one which is solved with definite diluted Sodium Hydroxide. This is why we want to reduce the poionous content as possible avoiding conc Alkaline Substances. Para-toluen Sulfo Chloride produced as by-product seems likely to be used as the followings: (1) the Ester, treated and manufactured with Alkaline Alchol, can be used as Alkalifing Reagent. (2) This Chloride can be used as Chlorifying Agent of Carbon Acid in Organic Synthesis. (3) this Chloride is used for the manufacture of Dialky1 Amine. (4) this Chloride is used for the manufacture of Chiramine T, Water disinfectant and Halazone. As the above, in order to keep our good health and to save foreign currency, we should not import the whole quantity of original crude sugar, but develop this area, by-products produced in the manufacture, and poisonless Saccharin in large quantity. Thus, if we export this in large quantity, taking the exclusive property of each market in the world, it is expected that this would contribute to economic development for exporting Korea.

      • 견/합성섬유 혼방품의 일욕염색(Ⅵ) : 산성염료/분산염료 염욕에서의 견/셀룰로오스 트리아세테이트의 염착거동 Adsorption Behavior of Acid Dyes/Disperse Dyes on Silk/Cellulose Triacetate

        金公朱,박미라,강영의,김애순 全北大學校 1994 論文集 Vol.38 No.-

        In one bath dyeing system of silk/cellulose triacetate(triactate) fiber blend fabric with acid/disperse dyes, adsorption behvior of acid dyes and disperse dyes on silk and triactate fabrics were examined. In the dyeing of triactate with the C.I. Disperse Red 19(Red 19) and the C.I. Disperse Red 60(Red 60) at 100℃, dye uptake with the Red 19 was higher than that with the Red 60. When the silk/triaceetate was dyed with Red 19 and the Red 60 at 100℃, dye uptake on triacetate was influenced by affinity of the dye to the silk fabric dyed together. In the treatment of the silk fabric dyed with the Red 19 and Red 60 in desorption bath with and without undyed triacetate, desorption of the dyes from the silk fabric was influenced by the affinity of the dyes to the triacetate. When the silk/triacetate was dyed with the Blue 80/Red 19 and Red 60 at 100℃, color of triacetate dyed with the Red 19 and Red 60 was not influenced by the Blue 80 but silk dyed with the Blue 80 was influenced by the Red 19.

      • 石灰石을 利用한 化學工業의 展望

        柳珙植 군산대학교 1980 論文集 Vol.1 No.-

        As stated above, we can realize that 'Lime stone' is one of the most important resources which are able to hare a dirrect connection with organic and inorganic chemical industry. 'Lime stone' is gengraphically distributed on a large scale and its deposits arc not only inexhaust ible but also rather superior ill its quality. Therefore this Lime stone Industry is considered to involve the possibility enough to he developed, and the industrialization of 'Lime stonc' call be one of new ways out of difficulty in chemical industry field in Korea, none-oil producing country, suffering with scarcity of resources in general. The materials of chemical industry being 'Lime stone', how to develop and bring up our chemical industry --- that relys on how to produce abundant electric power in low cost. Saying again, the basic problem is that electric power producing in low cost is the only way to bring lip our chemical industry. Therefore if it is possible to produce electric power abundantly in low cost by developing all the rivers possible and build up water power plants it is believed that we are able to bring up this 'Lime stone' industry with it and produce the same products from 'Lime stone' as we get from the petrolium chemical Industry.

      • KCI등재

        익산지역에서 자동 및 수동채취방식에 따른 강수의 화학적 특성 비교

        강공언 한국대기환경학회 2004 한국대기환경학회지 Vol.20 No.3

        In order to understand the precipitation acidity and chemical composition of ion species in Iksan area as well as to know the difference of chemical characteristics in precipitation samples from the viewpoint of precipitation sampling method, precipitation samples were collected by wet-only automatic precipitation sampler and hulk manual precipitation sampler in Iksan, from March 2003 to August 2003. The mean pH of precipitation was 5.0. There was a little significant difference in the mean value of pH between automatic and manual sampler. However, pH values of some precipitation samples were lower in automatic sampler than in manual sampler, especially in case of precipitation samples with small rainfall for March 2003. The mean concentrations of each ions in precipitation were generally a little higher in precipitation samples collected by the manual sampler than in those collected by the automatic sampler because of accumulation of dry deposition on the surface of glass funnel installed at the manual sampler during the sampling period of no rainfall. Dominant species determining the acidity of precipitation, were NH₄+ and nss-Ca^(2+) for cations and nss-SO₄^(2-) and NO₃- for anions. The mean concentration of NH₄+ and nss-Ca^(2+)j were 31 μeq/L and 9 μeq/L for the automatic sampler and 40 μeq/L and 16 μeq/L for the manual sampler, respectively. In addition, nss-SO₄^(2-) and NO₃- were 27 μeq/L and 13 μeq/L for the automatic sampler and 32 μeq/L and 17 μeq/L for the manual sampler, respectively. Although the concentrations of the acidifying ions of nss-SO₄^(2-) and NO₃- were about 3 times higher than those for foreign pristine sites, precipitation acidity were estimated to be natural due to the neutralization reaction of the alkaline species of NH₄+ and nss-Ca^(2+) with its higher concentrations. Considering the ratios of nss-SO₄^(2-)/NO₃- and NH₄+/nss-SO₄^(2-), it was found that ammonium sulphate was dominant in Iksan precipitation. The major non-sea salt ions were maximum concentrations for March, but decreased with increasing of precipitation amount.

      • 견/합성섬유 혼방품의 1욕염색(Ⅶ) : 견/아크릴로니트릴 섬유 혼방품의 염색거동 Adsorption Behavior of Silk/Acrylonitrile Fiber

        金公朱,김경수,전재홍,이화선 全北大學校 1995 論文集 Vol.40 No.-

        In one bath dyeing system of silk/acrylonitrile(acryl) fabric with acid/disperse dyes and acid/cation dyes, adsorption behavior of acid dyes, disperse dyes and cation dyes on silk and acryl fabrics were examined. In the dyeing of acryl with the C. I. Disperse Red 19(Red 19) and The C. I. Disperse Red 60(Red 60), dye uptake with Red 19 was higher than that with Red 60. When the silk and acryl fabric were dyed with C. I. Basic Red 27(Red 27), dye uptake on the acryl was higher than that on the silk. When the silk/acryl fabric was dyed with Red 19 and Basic 27, solid shade could be obtained with Red 19 but could not be obtained with Basic 27. In the dyeing of silk/acryl fabric dyed with Blue 80/Red 27 and C. I. Acid Blue 113(Blue 113)/C. I. Basic Blue 116(Blue 116), compatibility could be obtained with Blue 80/Red 27 but that could not be obtained with Blue 113/Blue 116.

      • 대기중 부유입자상물질의 통계적 해석에 관한 연구

        강공언,신대윤 조선대학교 생산기술연구소 1992 生産技術硏究 Vol.14 No.2

        In order to investigate the statistical analysis of ambient suspended particle at Seoul in Korea, airborne particulate matters were collected by High-Volume Air Sampler from April 1988 to May 1991, and size distribution of the aerosols were measured by filters on nine stages Andersen Air Sampler from January 1990 to December 1990. And with respect to seven components in the total suspended particulate, the factor analysis was performed. As a result of factor analysis by using the varimax rotation method, the chemical components in the TSP were able to characterize with two principal factors. The first factor (Factor 1) was considered to be a factor indicating the contribution of natural sources and the second factor(Factor 2) was a factor indicating the contribution of anthrophogenic sources. For concentration of size distribution measured by Andersen Air Sampler, tne factor analysis was also performed. As a result of factor analysis by using the varirnax rotation method, particle size distribution of atmospheric particulate was divided into two groups, coarse particle group was made by particles lager than 2.1㎛ in diameter and fine groups smaller than 1.1㎛ in diameter.

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