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Eslami Akbar,Mahdipour Fayyaz,Maleksari Hajar Sharifi,Varank Gamze,Ghasemi Seyed Mehdi,Nejatian Parisa,Bagheri Amin,Madihi-Bidgoli Soheila 한국화학공학회 2023 Korean Journal of Chemical Engineering Vol.40 No.12
CaO2 was activated by Fe(II) and ultrasound (US) irradiation to degrade 2,4-dichlorphenoxyacetic acid (2,4-D) for the first time. Among transition metals (Fe, Cu, Mn and Co), Fe(II) had the best performance for the activation of CaO2. The impact of pH, CaO2 and Fe(II) concentration was studied, and under optimal situation ∼91% of 2,4-D was degraded during 60 min reaction time. The quenching experiments showed that the hydroxyl radical was the main factor for the destruction of 2,4-D while superoxide anions had a minor role. The bicarbonate ions and acid humic exhibited a strong inhibitory effect on the performance of CaO2/US/Fe(II) process. Carbon and chlorine mineralization of 2,4-D degradation was investigated; around 41% of C and 35% of Cl were mineralized during 60 min reaction time. The function of CaO2/US/Fe(II) process was studied on real drainage and other organic pollutants, and the results showed that the CaO2/US/Fe(II) process can be practical for water treatment. Finally, intermediates of 2,4-D degradation were identified, a pathway was proposed, and the toxicity of intermediates was assessed by ECOSAR software.
Senem Yazici Guvenc,Aleyna Cebi,Emine Can-Güven,Ahmet Demir,Farshid Ghanbari,Gamze Varank 한국화학공학회 2022 Korean Journal of Chemical Engineering Vol.39 No.9
The treatability of biodiesel wastewater by the electrochemical peroxidation process following acidificationpretreatment was investigated. Box-Behnken design, one of the experimental designs of response surface methodology,was applied to optimize the process parameters for chemical oxygen demand (COD), oil-grease, and volatile fatty acids(VFAs) removal from biodiesel wastewater. The process parameters, i.e., applied current, H2O2/COD ratio, and reactiontime, were optimized and the total cost of the process was determined. After the acidification process as a pretreatment,the COD, oil-grease, and VFAs removal efficiencies were 25.4%, 68.7%, and 50%, respectively. Optimum conditionsdetermined by the developed model for maximum oil-grease removal (98.2%) were applied: current 1.0 A, H2O2/CODratio 0.4, and reaction time 32.8 minutes. This devised Box-Behnken model predicted removal efficiencies of 45.5%,98.2%, and 49.5% for COD, oil-grease, and VFAs, respectively. The total cost of the process determined by the modeland obtained from the validation experiments was 2.03 €/m3 and 1.97 €/m3, respectively. The results of the study showedthat the applied process was efficient in pollutant removal from acidified biodiesel wastewater and the Box-Behnkendesign can be applied to explain the mechanism of the process and optimize the process parameters.
Senem Yazici Guvenc,Yesim Daniser,Emine Can-Guven,Gamze Varank,Ahmet Demir 대한환경공학회 2023 Environmental Engineering Research Vol.28 No.1
In this study, sequential coagulation and electro-oxidation (EO) processes were applied to landfill leachate, which is highly contaminated and complex wastewater. Since the pollutant content of the leachate was too high, the coagulation process (poly aluminum chloride (PAC) as a coagulant) was applied as a pre-treatment to reduce the cost of the EO process. The Box-Behnken design of response surface methodology was used. The color number (CN) removal efficiency estimated by the model under optimum operating conditions was 80.1%, while it was 77.6% in the experimental studies performed under optimum conditions to verify the model conformity. Multi-metal oxide doped Ti (MMO/Ti), Pt doped Ti (Pt/Ti), and graphite were used as anode and stainless steel was used as cathode in the EO process. In the EO process in which Pt/Ti anode was used, chemical oxygen demand (COD), UV<SUB>254</SUB>, and CN removal efficiencies were 52.8, 68.1, and 85.6%, respectively under the conditions of applied current 1.25 A and the pH 5. The CN value decreased to 4.2 after the coagulation process and it was 0.6 at the effluent of the EO process.