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Shuguo Qu,Chenchen Zhang,Minhui Li,Yan Zhang,Lunbo Chen,Yushuai Yang,Bo Kang,Yiwei Wang,Jihai Duan,Weiwen Wang 한국화학공학회 2019 Korean Journal of Chemical Engineering Vol.36 No.12
Making inexpensive proton exchange membrane with high proton conductivity for the proton exchange membrane fuel cell (PEMFC) is still a challenging problem. Graphene oxide (GO) nanoparticles grafted with (3-aminopropyl) triethoxy silane (APTES) were prepared and then incorporated into sulfonated poly(ether ether ketone) (SPEEK) matrix by solution casting to make the composite proton exchange membrane. The obtained nanoparticles and composite membranes were characterized by XRD, FT-IR, Raman, TGA, SEM, and UTM. GO treated with the silane coupling agent improved the dispersion stability and compatibility of GO in SPEEK, which decreased the agglomeration of GO nanoparticles in the SPEEK membrane. The prepared nanocomposite membranes exhibited better water retention properties and proton conductivity. The proton conductivity of the SPEEK membrane with 2wt% amine functionalized GO (AGO) reached 11.32mS/cm at 120oC, which was 2.45-times higher than that of the pristine SPEEK membrane. The reason was that AGO nanoparticles disperse uniformly in the SPEEK membranes, which provides new channels for proton transfer. The potential application of this composite membrane in the PEMFC was indicated.
Numerical analysis study on the application of three-lobed vortex tube in low-production wells
Ruyi Gou,Chenchen Kang,Xun Luo 대한기계학회 2023 JOURNAL OF MECHANICAL SCIENCE AND TECHNOLOGY Vol.37 No.6
In order to solve the problem of fluid accumulation in horizontal gas wells and improve the fluid-carrying capacity and recovery efficiency of gas wells, this paper simulates three internal vortex tools using the commercial software ANSYS FLUENT, and analyzes the drainage recovery efficiency of the three vortex structures and the vortex characteristics of the downstream section vortex field. The results show that the axial velocity of the three-bladed spiral tube in the cyclonic field rotates quasi-periodically with the flow field compared with the internal vortex tube and the rifled tube, and the axial velocity, tangential velocity and vortex intensity of the three-bladed vortex tube guided flow field are the highest; meanwhile, the axial velocity, tangential velocity and vortex intensity of the three-bladed spiral tube guided flow field decay the fastest, and the line rifled tube decays the slowest. The liquid phase in the cyclonic field exhibits obvious spiral motion and maintains a long-distance cyclonic flow state under the action of cyclonic flow. The enhancement of the vortex intensity easily leads to the increase of liquid volume fraction and liquid film thickness at the tube wall. Through the analysis of the energy efficiency of the three structures, it is found that the three-leaf spiral tube is more suitable for the initial phase of drainage transport, while the internal vortex tube is more favorable for the stable phase of transport. The study of the gas-liquid swirl flow of the three swirl tools demonstrated the feasibility of the internal swirl tool for application in horizontal wells. It can provide theoretical guidance and practical basis for effective liquid filling with internal vortex tools in the future.