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Fukuzumi, Shunichi,Mandal, Sukanta,Mase, Kentaro,Ohkubo, Kei,Park, Hyejin,Benet-Buchholz, Jordi,Nam, Wonwoo,Llobet, Antoni American Chemical Society 2012 JOURNAL OF THE AMERICAN CHEMICAL SOCIETY - Vol.134 No.24
<P>Four-electron reduction of O<SUB>2</SUB> by octamethylferrocene (Me<SUB>8</SUB>Fc) occurs efficiently with a dinuclear cobalt-μ-1,2-peroxo complex, <B>1</B>, in the presence of trifluoroacetic acid in acetonitrile. Kinetic investigations of the overall catalytic reaction and each step in the catalytic cycle showed that proton-coupled electron transfer from Me<SUB>8</SUB>Fc to <B>1</B> is the rate-determining step in the catalytic cycle.</P><P><B>Graphic Abstract</B> <IMG SRC='http://pubs.acs.org/appl/literatum/publisher/achs/journals/content/jacsat/2012/jacsat.2012.134.issue-24/ja303674n/production/images/medium/ja-2012-03674n_0011.gif'></P><P><A href='http://pubs.acs.org/doi/suppl/10.1021/ja303674n'>ACS Electronic Supporting Info</A></P>