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Inexpensive, upscalable nanotube growth methods
Z.E. Horvath,K. Kertesz,L. Petho,A.A. Koos,L. Tapaszto,Z. Vertesy,Z. Osvath,Al. Darabont,P. Nemes-Incze,Zs. Ssrkozi,L.P. Bir? 한국물리학회 2006 Current Applied Physics Vol.6 No.2
Despite of the very promising foreseen applications, the use of carbon nanotubes in wider range is still limited by the high pro-duction costs. In this paper, our latest results concerning two inexpensive methods of carbon nanotube growth with the promise ofindustrial upscaling are presented. In case of the DC ‘‘arc in water’’ method, the eect of the angle of the two electrodes on theproduct yield was investigated. The highest nanotube yield and lowest amount of impurities were found at 90. electrode angles.zene/ferrocene solution in case of the injection CVD or ‘‘spay pyrolysis’’ method. Toluene, xylene, cyclohexane, cyclohexanone,n-hexane,n-heptane,n-octane andn-pentane were used as carbon source and cobaltocene and nickelocene as catalyst source. All thesecompounds were found to be suitable for nanotube production. The highest yield and the best quality were obtained when a mixtureof ferrocenenickelocene was used as catalyst and xylene as carbon source