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        Silver and palladium nanoparticle embedded poly(n-isopropylacrylamide-co-2- acrylamido-2-methylpropane sulfonic acid) hybrid microgel catalyst with pH and temperature dependent catalytic activity

        Abdul Haleem,Sidra Bibi Syaal,Muhammad Ajmal,Jaweria Ambreen,Sajid Rauf,Nasir Ali,Saz Muhammad,Afzal Shah,Muhammad Abid Zia,Muhammad Siddiq 한국화학공학회 2020 Korean Journal of Chemical Engineering Vol.37 No.4

        Here in, we demonstrate facile fabrication of silver and palladium nanoparticles in dual responsive poly(Nisopropylacrylamide- co-2-Acrylamido-2-methylpropane sulfonic acid) microgel with temperature- and pH-dependent catalytic potential. Palladium-based catalyst showed better catalytic efficiency as compared to silver-based catalyst for degradation of Rhodamine-B and P-Nitrophenol in aqueous medium under the same set of reaction conditions. The responsive nature of the microgel was found to be useful to tune the catalytic activity of the as-prepared catalysts, and reduction rate was enhanced with the pH and temperature elevation of the reaction medium; however, the increasing trend was slowed in the volume phase transition region of the microgel. Under a specific set of reaction conditions, the reduction of Rhodamine-B was as fast as 0.968 and 0.571 min1 when catalyzed with palladium and silver based catalysts, respectively. The hydrodynamic radius of the particles of microgel support was found to be in the range of 65- 180 nm when pH and temperature of the medium were varied in the range of 2-12 and 25-45, respectively. The estimated diameter of silver and palladium nanoparticles fabricated in the microgel support under the same set of reaction conditions was 9-15 and 7-11 nm, respectively.

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        Size effect on strength of Fiber-Reinforced Self-Compacting Concrete (SCC) after exposure to high temperatures

        M. Eren Gülşan,Khamees N. Abdulhaleem,Ahmet E. Kurtoğlu,Abdulkadir Çevik 사단법인 한국계산역학회 2018 Computers and Concrete, An International Journal Vol.21 No.6

        This pioneer study investigates the size effect on the compressive and tensile strengths of fiber-reinforced selfcompacting concrete (FR-SCC) with different specimens, before and after exposure to elevated temperatures. 432 selfcompacting concrete (SCC) specimens with two concrete grades (50 and 80MPa) and three steel fiber ratios (0%, 0.5% and 1%) were prepared and tested. Moreover, based on the experimental results, new formulations were proposed to predict the residual strengths for different specimens. A parametric study was also carried out to investigate the accuracy of proposed formulations. Residual strength results showed that the cylinder specimen with dimensions of 100×200 mm was the most affected, while the cube with a size of 100 mm maintained a constant difference with the standard cylinder (150×300 mm). Temperature effect on the cube specimen (150 mm) was the least in comparison to other specimen sizes and types. In general, provision of steel fibers in SCC mixtures resulted in a reduction in temperature effect on the variance of a conversion factor. Parametric study results confirm that the proposed numerical models are safe to be used for all types of SCC specimens.

      • Rehabilitation of normal and self-compacted steel fiber reinforced concrete corbels via basalt fiber

        Gulsan, Mehmet Eren,Al Jawahery, Mohammed S.,Alshawaf, Adnan H.,Hussein, Twana A.,Abdulhaleem, Khamees N.,Cevik, Abdulkadir Techno-Press 2018 Advances in concrete construction Vol.6 No.5

        This paper investigates the behavior of normal and self-compacted steel fiber reinforced concrete (SCC-SFRC) corbels rehabilitated by Basalt Fiber Mesh (BFM) and Basalt Fiber Fabric (BFF) for the first time in literature. The research objective is to study the effectiveness of BFM and BFF in the rehabilitation of damaged reinforced concrete corbels with and without epoxy injection. The experimental program includes two types of concrete: normal concrete, and self-compacted concrete. For normal concrete, 12 corbels were rehabilitated by BFM without injection epoxy in cracks, with two values of compressive strength, three ratios of steel fiber (SF), and two values of shear span. For self-compacted concrete, 48 corbels were rehabilitated with different parameters where 12 corbels were rehabilitated by BFM with and without epoxy injection, 18 heated corbels with three different high-temperature level were rehabilitated by repairing cracks only by epoxy injection, and 18 heated corbels with three different high-temperature level were rehabilitated by repairing cracks by epoxy and wrapping by BFF. All 48 corbels have two values of compressive strength, three values volumetric ratios of SF, and two values of the shear span. Test results indicate that RC corbels rehabilitated by BFM only without injection did not show any increase in the ultimate load capacity. Moreover, For RC corbels that were repaired by epoxy without basalt wrapping, the ultimate load capacities showed an increase depending on the mode of failure of corbels before the rehabilitation. However, the rehabilitation with only crack repairing by epoxy injection is more effective on medium strength corbels as compared to high strength ones. Finally, it can be concluded that use of BFF is an effective and powerful technique for the strengthening of damaged RC corbels.

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