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중금속 이온과 질소-황을 포함하는 포단드와의 착물형성에 관한 연구
정징운,이선하,최규성,강동현 慶南大學校 附設 基礎科學硏究所 1997 硏究論文集 Vol.10 No.-
The stability constant, enthalpy, and etropy changes of complexation of heavy metal ions (Zn²*, Cd²*) with podands containing nitrogen-sulfur donors such as tri(phenylthio-2-ethyl)amine (Podand Ⅰ), tri(benzylmercapto-2-ethyl)amine(Podand Ⅱ), and tetra(phenylthio-2-ethyl)ethylenediamine (Podand Ⅲ) have been determined by using potentiometric titration in 95% MeOH at various temperature. We observed the Podand Ⅲ ligand showed the largest protonation constant. The values of protonation constant and stability constant for Zn(Ⅱ), and Cd(Ⅱ) ions among three different ligands were increased as following order, Podand Ⅰ< Podand Ⅱ< Podand Ⅲ. In addition, thermodynamic parameters ΔH and TΔS of Zn(Ⅱ), Cd(Ⅱ) complexes have studied.
Cu(Ⅱ) 이온과 질소-황을 가진 포단드와의 착물 형성에 관한 연구
최규성,정징운 慶南大學校 附設 基礎科學硏究所 1996 硏究論文集 Vol.8 No.-
The stability constants, enthalpy, and entropy changes of complexation of Cu(Ⅱ) ion with sulfur-containing podand ligands such as tri(phenylthio-2-ethyl)amine(Podand Ⅰ), tetra(phenylthio-2-ethyl)ethylendiamine (Podand Ⅱ) have been determined by uv-vis spectrophotometer in 95% MeOH at various temperature. From the results, the followings have been obtained. Cu(Ⅱ) ion forms a 1:1 complex with these ligands, the order of stability constants and enthaply changes is Podand Ⅰ <Podand Ⅱ, entropy changes is Podand Ⅰ> Podand Ⅱ.