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pH를 달리하여 제조한 3가철 첨착 활성탄에 의한 구리 제거특성 평가
양재규(Jae Kyu Yang),이남희(Nam Hee Lee),이승목(Seung Mok Lee) 大韓環境工學會 2008 대한환경공학회지 Vol.30 No.3
본 연구에서는 다양한 pH 조건에서 활성탄에 Fe(III)를 첨착시킨 Fe-첨착활성탄(Fe-AC)을 제조하였으며, 제조한 Fe-AC가 여과재질로서의 안정성 유무를 파악하기 위하여 내산성 실험을 수행하였다. 또한 Fe-AC의 중금속 제거능을 파악하기 위하여 회분식 실험을 수행하였다. 흡착제의 안정성 실험결과 모든 pH 조건에서 시간이 지날수록 철의 용출량은 증가하였지만, 용액의 pH가 높아질수록 철의 용출량이 감소하는 경향을 보였다. 용액의 pH를 2로 고정했을 경우 시간경과에 따라 철의 용출량이 점차 증가하여 12시간 후에는 Fe-AC에 함유된 총 철 함량의 13%가 용출되었으나, pH 3 이상에서 철의 용출량은 급격히 줄어들어서 무시할 수 있는 것으로 나타났다. 회분식 실험결과 Fe-AC에 의한 Cu(II) 제거는 흡착질의 농도가 감소하고 용액의 pH가 증가할수록 Cu(II)의 제거율은 증가하는 경향을 보였다. 모델링에 의한 흡착결과 예측은 이중확산층 이론에 의한 inner-sphere type의 표면착물화를 고려하여 MINTEQA₂ 프로그램을 사용하여 실시하였다. Fe-impregnated activated carbon(Fe-AC) was prepared by Fe(III) loading on activated carbon(AC) in various preparation pH. In order to evaluate the stability of Fe-AC, dissolution of iron from Fe-AC in acidic conditions was measured. In addition, batch experiments were conducted to monitor the removal efficiency of copper by Fe-AC. Results of stability test for Fe-AC showed that the amount of extracted iron increased with contact time but decreased with increasing solution pH. The dissolved amount of iron gradually increased at solution pH 2 and finally 13% of the total iron loaded on activated carbon was extracted after 12 hr. However dissolution of iron was negligible over solution pH 3. Removal of Cu(II) by Fe-AC was greatly affected by solution pH and was decreased as solution pH increased as well as initial Cu(II) concentration decreased. Surface complexation modeling was performed by considering inner-sphere complexation reaction and using the diffuse layer model with MINTEQA₂ program.
6가 크롬 처리를 위한 알루미늄 산화물을 함유한 재생 분말 폐기물의 적용
임재우(Jae Woo Lim),김태환(Tae Hwan Kim),강형식(Hyung Sik Kang),김도선(Do Son Kim),김한선(Han Seon Kim),조석희(Seok Hee Cho),양재규(Jae Kyu Yang),장윤영(Yoon Young Chang) 大韓環境工學會 2009 대한환경공학회지 Vol.31 No.3
본 연구에서는 알루미늄 산화물을 함유한 재생 분말 폐기물에 의한 Cr(VI)의 제거특성을 조사하였다. 가공하지 않은 폐기물의 유기물을 제거하기 위해 550℃에서 소성하여 재생 분말 폐기물(RPW)을 준비하였다. 수용액 상에서 Cr(VI)의 흡착 경향에 관한 연구를 위해 회분식 반응장치를 이용하여 pH 변화, 흡착 속도, 등온 흡착 실험을 4가지 다른 이온세기 화학종(NO₃-, CO₃<sup>2-</sup>, SO₄<sup>2-</sup>, PO₄(3-))의 존재 하에서 수행하였다. SO₄<sup>2-</sup>와 PO₄(3-)가 존재할 때는 전체 pH 범위에서 크롬의 흡착이 크게 감소하였다. 반면 NO₃-와 CO₃<sup>2-</sup>에 의한 흡착 방해의 영향은 SO₄<sup>2-</sup>와 PO₄(3-)에 의한 것보다 상대적으로 낮았다. NO₃-와 CO₃<sup>2-</sup>의 존재 하에 Cr(VI) 흡착은 pH 4.5에서 최대로 나타났다. 이온세기 화학종의 농도가 증가함에 따라 Cr(VI)의 흡착은 감소하였다. 이러한 결과를 토대로 할 때 RPW와 Cr(VI) 사이의 흡착은 외부배위권 착물을 통하여 발생되는 것으로 사료된다. RPW에 의한 Cr(VI)의 흡착은 2차 반응으로 잘 표현되었다. Langmuir 등온흡착식을 이용하여 pH 3에서 RPW에 의한 Cr(VI)의 최대 흡착량을 구한결과 NO₃-, CO₃<sup>2-</sup>, SO₄<sup>2-</sup>, PO₄(3-)가 이온세기 화학종으로 있을 때 각각 11.1, 10, 3.33, 5 mg/g으로 얻어졌다. In this research, the removal capacity of Cr(VI) by the reused powdered wastes (RPW) containing aluminium oxides was studied. As a pre-treatment process for the preparation of calcined wastes, calcination was conducted at 550℃ to remove organic fraction in the raw wastes. In order to study the adsorption trend of Cr(VI) ions from aqueous solutions, the pH-edge adsorption, adsorption kinetic and adsorption isotherm were investigated using a batch reactor in the presence of four different background electrolytes(NO₃-, CO₃<sup>2-</sup>, SO₄<sup>2-</sup>, PO₄(3-)). Cr(VI) adsorption was greatly reduced in the presence of SO₄<sup>2-</sup> and PO₄(3-) over the entire pH range. Meanwhile the inhibition effect by NO₃- and CO₃<sup>2-</sup> was relatively lower than that by SO₄<sup>2-</sup> and PO₄(3-). Cr(VI) adsorption was maximum around pH 4.5 in the presence of NO₃- and CO₃<sup>2-</sup>. As the concentration of background electrolytes increased, Cr(VI) adsorption decreased. This result mightly suggests that adsorption between the surface of RPW and Cr(VI) occurs through outer-sphere complex. Cr(VI) adsorption onto the RPW was well described by second-order kinetics. From the Langmuir isotherm at initial pH 3, the maximum adsorbed amount of Cr(VI) onto the RPW was 11.1, 10, 3.3, 5 mg/g in the presence of NO₃-, CO₃<sup>2-</sup>, SO₄<sup>2-</sup>, and PO₄(3-), respectively.
사용종료 매립지 선별토양의 메탄 발생 분석 및 토양경작기술 적용 효과 연구
김경,양재규,장윤영,Kim, Kyung,Yang, Jae-Kyu,Chang, Yoon-Young 한국지하수토양환경학회 2010 지하수토양환경 Vol.15 No.5
In this study, methane production by reuse of screened soil of landfill was estimated and the effect of application of landfarming for the reduction of methane was investigated. The study soil sampled from S closed landfill contains VS 9.8~12.8% and its BOD/COD is 0.31~0.33 which is more than three times over 0.1, the BOD/COD stabilization criteria of Ministry of Environment. The effective remediation technology for the reduction of organics of soil, landfarming was applied to the screened soil for 60 days. VS and TPH removal showed 5.2~8.3% and 67~74% respectively, and the reduction of VS until 30 day charged 70% of the total reduction. BMP test showed 27.77~30.46 mL $CH_4$/g VS and total methane production from total screened soil for remediation is expected about 260.4 $CH_4$ ton. Expected amount of methane production of the screened soil by landfarming application is 12.9 $CH_4$ ton, which shows 95% gas reduction effect and landfarming is effective for the reduction of methane production from screened soil of landfill.