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탄소나노튜브로 개질된 탄소종이 기반 젖산산화효소 - 카탈레이즈 전극 제작 및 특성 분석
김창준,시키,셀바라잔 바르시니,양영일,김혁한 한국화학공학회 2023 Korean Chemical Engineering Research(HWAHAK KONGHA Vol.61 No.4
This study aimed to investigate the impact of enhancing the electrode conductivity and mitigating the production of hydrogen peroxide - a by-product arising from lactate oxidation – on the performance of lactate electrodes. The electrical conductivity of the electrode was improved by modifying the surface of carbon paper with single-walled carbon nanotubes. Catalase was introduced to effectively eliminate the hydrogen peroxide produced during the lactate oxidation reaction. The carbon paper electrode, with simultaneous immobilization of both lactate oxidase and catalase, yielded a current 1.7 times greater than the electrode where only lactate oxidase was immobilized. The electrode in which lactate oxidase and catalase were co-immobilized on the surface of carbon paper modified with single-walled carbon nanotubes, produced a current of 171 μA, which was more than twice as much current as the carbon paper with only lactate oxidase immobilized. The optimized electrode showed a linear response up to lactate concentration of 20 mM, confirming that it can be used as a sensor electrode.
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젖산 산화효소-카탈라아제-미토콘드리아 전극 제작 및 특성 분석
김창준,시키,마니칸단 키에르티 부샨,최영봉 한국화학공학회 2024 Korean Chemical Engineering Research(HWAHAK KONGHA Vol.62 No.3
젖산 전극은 환자의 건강상태와 스트레스 수준, 및 운동선수의 피로도를 실시간으로 모니터링하는 젖산 센서 또는젖산 연료전지 전극으로 활용될 수 있다. 본 연구에서는 젖산 산화효소, 카탈라아제, 미토콘드리아로 구성된 고성능 전극을 제작하고 전극의 표면분석 및 전기화학적 특성을 조사하였다. 단일벽 탄소나노튜브로 개질된 탄소종이(CPSWCNT) 는 개질 전보다 전기 전도성이 크게 향상되었다. 젖산 산화효소, 카탈라아제, 그리고 미토콘드리아가 부착된전극(CP-SWCNT-LOx-Cat-Mito)은 젖산 산화효소와 카탈라아제가 부착된 전극에 비하여 많은 전류를 생산하였다. 빌리루빈 산화효소(BOD)가 부착된 전극(CP-SWCNT-BOD)이 생산하는 환원전류량은 전해질의 산소 존재 유무에 따라크게 영향을 받았다. CP-SWCNT-LOx-Cat-Mito (anode)와 CP-SWCNT-BOD (cathode)로 구성된 연료전지는 133 μA/ cm2로 방전 시 0.2 V의 셀 전위를 유지하며 29 μW/cm2의 전력을 생산하였다. 본 연구결과는 미토콘드리아가 젖산 센서 및 연료전지 성능 향상에 필수적인 생체물질임을 시사한다. The lactate electrode can be utilized either as an electrode for lactate sensor to monitor the patient's health status, stress level, and athlete's fatigue in real time or lactate fuel cell. In this study, we fabricated a high-performance electrode composed of lactate oxidase, catalase, and mitochondria, and investigated the surface analysis and electrochemical properties of this electrode. Carbon paper modified with single-walled carbon nanotubes (CP-SWCNT) had significantly improved electrical conductivity compared to before modification. The electrode to which lactate oxidase, catalase, and mitochondria were attached (CP-SWCNT-LOx-Cat-Mito) produced a higher current than the electrode to which lactate oxidase and catalase were attached. The amount of reduction current produced by the bilirubin oxidase (BOD)-attached electrode (CP-SWCNT-BOD) was greatly affected by the presence or absence of oxygen in the electrolyte. The fuel cell composed of CP-SWCNT-LOx-Cat-Mito (anode) and CP-SWCNT-BOD (cathode) produced maximum power (29 μW/ cm2) at a discharge current density of 133 μA/cm2. From this study, we had proved that mitochondria is essential for improving lactate sensor and fuel cell performance.
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전기화학 증착법을 이용한 그래핀 개질 Indium Tin Oxide 전극 제작 및 효소 전극에 응용
왕설 ( Xue Wang ),시키 ( Ke Shi ),김창준 ( Chang-joon Kim ) 한국화학공학회 2022 Korean Chemical Engineering Research(HWAHAK KONGHA Vol.60 No.1
Graphene has a large surface area to volume ratio and good mechanical and electrical property and biocompatibility. This study described the electrochemical deposition and reduction of graphene oxide on the surface of indium tin oxide (ITO) glass slide and electrochemical characterization of graphen-modified ITO. Cyclic voltammetry was used for the deposition and reduction of graphene oxide. The surface of graphen-coated ITO was characterized using scanning electron microscopy and energy dispesive X-ray spectroscopy. The electrodes were evaluated by performing cyclic voltammetry and electrochemical impedance spectroscopy. The number of cycles and scan rate greatly influenced on the coverage and the degree of reduction of graphene oxide, thus affecting the electrochemical properties of electrodes. Modification of ITO with graphene generated higher current with lower charge transfer resistance at the electrode-electrolyte interface. Glucose oxidase was immobilized on the graphene-modified ITO and has been found to successfully generate electrons by oxidizing glucose.
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