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Co(ll)이온과 N₂O₂계 거대고리 리간드와의 착물형성에 관한 연구
최규성,성찬기,정윤숙 慶南大學校 附設 基礎科學硏究所 1989 硏究論文集 Vol.1 No.-
The protonation constants for the macrocyclic ligands containing nitrogen and oxygen donors such as 1, 12-diaza-3,4 : 9, 10-dibenzo-5, 8-dioxacyclopentadecane(NtnOenH₄), 1, 13-diaza -3,4 : 10, 11-dibenzo-5, 9-dioxacyclohexadecane( NtnOtnH₄) have been determined by potentiometric titration at 25℃. In order to obtain the enthalpy and entropy changes of complexation reaction of Co(II)ion with these ligands, the stability constants have been measured by uv-vis spectrophotometric method at 20~45℃. Protonation constants and stability constants have been found to be effected by the basicities of the macrocyclic ligands. The complexation reactions are exothermic and show the positive entropy changes. ?? studies showed that the stepwise additions of Co(II) ion the macrocyclic ligands of constant concentration induced spectral changes. The large chemical shifts of protons nearest aside the nitrogen were noticeable with the addition of Co(II) ion.