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비수용매속에서 Eriochrome Black-T의 폴라로그래피적 거동에 관한 연구
金世奉,金一斗,丁梧鎭 조선대학교 기초과학연구소 1988 自然科學硏究 Vol.11 No.1
The electrochemical reduction mechanism of the E. C. B. T in dimethylsulfoxide and system on the addition of proton donor with water was studied. A single two-electron wave, irreversible step below pH5.5 was observed and also irreversible step above pH 6. 1 to pH10.6 was obtained two one-electron waves, and two two-electron waves, respectively. A probable mechanism of the reduction step of each pH range has been proposed.