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한종대,김문평 昌原大學校 基礎科學硏究所 1997 基礎科學硏究所論文集 Vol.9 No.-
To investigate the potential of coal fly ash for landfill cover material and adsorbent of heavy metals in waste water, the use of coal fly ash for removal of heavy metals such as Pb, Cd, Cu and Zn from aqueous solution was investigated using batch adsorption and subsequent desorption. And the effect of organic compounds such as C(glucose). PO₄-P and NH₃-N on the removal efficiency of heavy metals was also investigated. The removal capacity and removal efficiency of fly ash for heavy metals were observed to be greater than those of the soil mostly used as landfill cover material. The removal capacity increased in the presence of organic compounds. Coal fly ash showed the preference for heavy metals in sequence of Cd>Cu>Zn>Pb, and showed an excellent removal capacity for Cd and Cu of 10 ㎎ metal per g of coal fly ash. The PO₄-P of 5 ㎎ per g of coal fly ash was removed, but the removal capacity did not increased with increased concentration. The NH₃-N and C(glucose) were hardly removed by coal fly ash. The dominant possible mechanisms are precipitation on the fly ash surface, precipitation in the fly ash pore and adsorption. The use a mixture of coal fly ash and soil as landfill cover material will enhance leachate stabilization and refuse decomposition by the alkalic property of coal fly ash. And the use of coal fly ash in cover material will provide the source of inexpensive cover material, and an outlet for coal fly ash. the coal fly ash also showed the potential as adsorbent of heavy metals in waste water.