합성 조건이 분무열분해 공정에 의해 합성되는 Co₃O₄ 분말의 특성에 미치는 영향

김도엽,주서희,구혜영,홍승권,강윤찬,Kim, Do-Youp,Ju, Seo-Hee,Koo, Hye-Young,Hong, Seung-Kwon,Kang, Yun-Chan 한국재료학회 2006 한국재료학회지 Vol.16 No.1

[ $Co_3O_4$ ] particles with non-aggregation characteristics were prepared by various conditions such as preparation temperature, flow rate of carrier gas, and concentration of spray solution using spray pyrolysis. The morphology and crystallinity of the preformed particles obtained by spray pyrolysis at various conditions affected the mean size and morphology of the post-treated $Co_3O_4$ particles. The preformed particles with hollow and porous morphology obtained from spray solution with citric acid and ethylene glycol turned to $Co_3O_4$ particles with nano size, regular morphology and non-aggregation characteristics after post-treatment at $800^{\circ}C$. On the other hand, the preformed particles obtained by the preparation conditions of short residence time of particles inside hot wall reactor and high reactor temperature turned to $Co_3O_4$ particles with aggregated morphology after post-treatment. The mean crystallite size and particle size of the $Co_3O_4$ particles prepared from optimum preparation conditions were 47 nm and 210 nm at post-treatment temperature of $800^{\circ}C$.

저압 분무열분해법에 의해 합성된 나노 크기의 코발트 산화물 입자의 특성

주서희,김도엽,강윤찬,Ju, Seo-Hee,Kim, Do-Youp,Kang, Yun-Chan 한국재료학회 2006 한국재료학회지 Vol.16 No.9

Nano-sized cobalt oxide powders were prepared by low pressure spray pyrolysis process. The precursor powders obtained by low pressure spray pyrolysis process from the spray solution with ethylene glycol had several microns size and hollow structure. The precursor powders obtained from the spray solution with optimum concentration of ethylene glycol formed the nano-sized cobalt oxide powders with regular morphology after post-treatment without milling process. On the other hand, the cobalt oxide powders obtained from the spray solution without ethylene glycol had submicron size and spherical shape before and after posttreatment. The mean size of the cobalt oxide powders formed from the spray solution with concentration of ethylene glycol of 0.7M was 180 nm after post-treatment at temperature of $800^{\circ}C$. The mean size of the powders could be controlled from several tens nanometer to micron sizes by changing the post-treatment temperatures in the preparation of cobalt oxide powders by low pressure spray pyrolysis process.

지하굴착 이격거리에 따른 흙막이벽체 거동에 대한 실험적 연구

박종덕,안창균,김도엽,이석원,Park, Jong-Deok,Ahn, Chang-Kyun,Kim, Do-Youp,Lee, Seok-Won 한국터널지하공간학회 2016 한국터널지하공간학회논문집 Vol.18 No.2

본 연구에서는 지상구조물 건설을 위하여 흙막이 벽체를 이용하여 지하굴착이 이루어진 지역에 근접하여 새로운 지하공간이 신설될 때, 지하굴착과 흙막이 벽체간의 이격거리에 따른 흙막이 벽체에 작용하고 있던 토압의 변화 및 지표 침하 변화를 실험적으로 연구하였다. 지하공간 굴착 단계별로 흙막이 벽체의 토압 변화 및 지표 침하를 측정할 수 있는 길이 160 cm, 높이 120 cm의 모형 토조를 제작했다. 실험은 균일하게 조성된 사질토 지반에서 하부 지반에 변위를 가하고, 수직한 흙막이 벽체의 토압 변화 및 지표면 침하를 확인하는 방식으로 수행하였다. 모형실험은 인접한 지하공간 굴착에 따른 흙막이 벽체의 높이별 토압을 측정하기 위하여 흙막이 벽체를 모사하는 우측 벽체 10개 및 지하공간 굴착을 모사하는 하부 벽체 5개로 구성하고 하부벽체를 거동시킴으로서 지하굴착을 모사하였다. 실험 결과, 하부 1단 벽체의 거동 시에는 흙막이 벽체의 토압에 변화가 발생하였으나, 하부 3단의 경우는 지하 굴착이 흙막이 벽체와 충분히 이격되어 토압변화가 크게 발생하지 않았다. 하부 1단 벽체를 굴착한 결과, 우측 하단부 벽체 주변의 응력이 감소되고, 우측 중간부 벽체 주변으로 응력이 재분배되는 아칭현상을 증명할 수 있었다. The changes in earth pressure and ground settlement due to the underground excavation nearby the existing retaining wall according to the separation distance between underground excavation and retaining wall, were studied experimentally. A soil tank having 160 cm in length and 120 cm in height, was manufactured to simulate the underground excavation like tunnel by using 5 separated bottom walls. The variation of earth pressure was measured according to the excavation stages by using 10 separated right walls simulating the retaining wall. The results showed that the earth pressure was changed by the lowering of first bottom wall(B1), however the earth pressure was not changed significantly by the lowering of third bottom wall(B3) since B3 had sufficient separation distance from retaining wall. Lowering of first bottom wall(B1) induced the decrease of earth pressure in lower part of retaining wall, on the contrary, lowering of first bottom wall(B1) induced the increase of earth pressure in middle part of retaining wall proving the arching effect.

고온 분무열분해 공정에 의한 녹색 발광의 BAM:Mn 형광체 합성

주서희,구혜영,김도엽,강윤찬,Ju Seo Hee,Koo Hye Young,Kim Do Youp,Kang Yun Chan 한국재료학회 2005 한국재료학회지 Vol.15 No.8

Green-light emitting $BaMgAl_{10}O_{19}:Mn^{2+}$ (BAM:Mn) phosphor particles were prepared by spray Pyrolysis. The effect of reactor temperature and flow rate of carrier gas in the spray Pyrolysis on the morphology, crystallinity and photoluminescence characteristics under vacuum ultraviolet were investigated. The morphology of the as-Prepared Particles obtained by spray Pyrolysis had spherical shape and non-aggregation characteristics regardless of the reactor temperature. The spherical shape of the as-prepared Particles obtained by spray pyrolysis at low temperature disappeared after Post-treatment. On the other hand the as-Prepared Particles obtained by spray Pyrolysis at $1600^{\circ}C$ maintained spherical shape and non-aggregation characteristics after post-treatment at $1400^{\circ}C$ for 3 h under reducing atmosphere. The BAM:Mn Phosphor Particles Prepared by spray Pyrolysis at different reactor temperatures had pure crystal structure and high photoluminescence intensities under vacuum ultraviolet after post-treatment. BAM:Mn phosphor particles prepared by spray Pyrolysis at low How rate of carrier gas had complete spherical shape and filed morphology and high photoluminescence intensity after post-treatment under reducing atmosphere.

사질토 지반에서 흙막이벽체-지하공간 연속 굴착에 따른 지반거동에 대한 실험적 연구

박종덕,유정선,김도엽,이석원,Park, Jong-Deok,Yu, Jeong-Seon,Kim, Do-Youp,Lee, Seok-Won 한국터널지하공간학회 2015 한국터널지하공간학회논문집 Vol.17 No.3

본 연구에서는 흙막이벽과 같은 수직굴착과 터널과 같은 지하공간의 연속적인 굴착에 따른 지반 거동과 토압 변화를 실험적으로 연구하였다. 굴착 단계별로 벽체 거동, 토압 변화, 그리고 지표 침하의 측정이 가능한 길이 160cm, 높이 120cm의 모형 토조를 제작하였다. 실험은 균일하게 조성된 사질토 지반에서 벽체에 임의의 변위를 가하고, 토압 변화와 지표 침하를 확인하는 방식으로 수행하였다. 모형실험은 흙막이벽과 지하공간의 연속적인 시공을 모사하기 위하여 흙막이벽 굴착을 모사하는 우측벽체 10개 및 지하공간 굴착을 모사하는 하부벽체 5개를 순서대로 거동시켜 모사하였다. 실험 결과, 벽체의 주동변위로 감소된 토압이 주변 벽체로 분담되는 아칭현상이 모든 벽체에서 발생함을 확인하였다. 연속되는 시공을 모사한 실험에서 phase마다 아칭현상을 확인할 수 있으나, 하부1단 벽체의 거동 시, 우측10단 벽체는 다른 경우와 달리 토압이 50%정도만 회복됨을 보였다. The ground movement and changes in earth pressure due to the consecutive construction of retaining wall and underground space were studied experimentally. A soil tank having 160 cm in length and 120 cm in height, was manufactured to simulate the vertical excavation like retaining wall by using 10 separated right side walls and underground space excavation like tunnel by using 5 separated bottom walls. The variation of earth pressure and surface settlement were measured according to the excavation stages. The results showed that the decrease of earth pressure due to the wall movement can cause the increase of earth pressure of the neighboring walls proving the arching effect. Experiments simulating continuous construction sequence also identified arching effect, however only 50% of earth pressure was restored on the 10th right side wall due to the movement of 1st bottom side wall unusually.

실리카 함유 콜로이달 분무용액으로부터 합성된 BAM:Mn 형광체

주서희,구혜영,홍승권,김도엽,강윤찬,Ju, Seo-Hee,Koo, Hye-Young,Hong, Seung-Kwon,Kim, Do-Youp,Kang, Yun-Chan 한국재료학회 2006 한국재료학회지 Vol.16 No.2

[ $BaMgAl_{10}O_{19}:Mn^{2+}$ ](BAM:Mn) phosphor particles with spherical shape were prepared by spray pyrolysis from colloidal solution with silica. The phosphor particles prepared by spray pyrolysis from aqueous solution had irregular morphology after high temperature post-treatment. On the other hand, the phosphor particles prepared from spray solution with colloidal silica had spherical shape after post-treatment. Colloidal silica used as additive improved the spherical shape and filled morphology of the precursor particles prepared by spray pyrolysis. The precursor particles with filled structure produced the BAM:Mn phosphor particles with spherical shape and non-aggregation characteristics after post-treatment at $1400^{\circ}C$ under reducing atmosphere. The phosphor particles prepared from colloidal solutions formed the crystal structure of BAM:Mn phosphor irrespective of the silica contents. The BAM:Mn phosphor particles prepared from aqueous and colloidal solutions had similar photoluminescence intensities under vacuum ultraviolet.

Design and Performance Test of a Rotary Actuator for Side Tilting Excavator Bucket

박민수(Min Su Park),이준석(Jun Seok Lee),김도엽(Do Youp Kim),이응석(Eung Suk Lee) Korean Society for Precision Engineering 2017 한국정밀공학회지 Vol.34 No.1

Generally, a working excavator has only one directional bucket tilting angle, which is up-forward. However, side direction rotation of the bucket would allow variety of working output. We designed a hydraulic rotary actuator comprising a double rod hydraulic cylinder with a rack-pinion gear set for use in excavator bucket with side tilting mechanism, thus converting the linear to angular motion. The proposed side tilting rotary actuator was designed with parts suitable for medium size of heavy duty excavator. These mechanical parts were inexpensive to purchase and the manufacturing cost was reasonable. The proposed mechanism is potentially useful for excavator with variety of working output.