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4차 염화 가교화된 Vinylbenzyl chloride 공중합체를 감습막으로 이용한 습도센서의 감습 특성
이성수,공명선,Lee, Seong-Su,Gong, Myeong-Seon 한국재료학회 2000 한국재료학회지 Vol.10 No.12
고분자막 습도센서의 감습재료로 사용하기 위하여 vinylbenzyl chloride (VBC), methyl methacrylate (MMA) 그리고 2-hydroxyethyl methacrylate (HPMA)의 여러 가지 조성의 공중합체를 합성하여, 이를 전극에 도포하고 N, N, N', N'-tetraethylene diamine으로 4차 암모늄화 시켜 최종 습도센서를 제조하였다. 상대습도에 따른 저항 변화를 측정한 결과, 공중합체에서 MMA의 조성이 증가하면 저항이 증가하였으며, HEMA의 도입은 친수성기의 작용으로 저항의 증가는 크지 않았으며 강습막의 기판과의 접착성은 크게 향상되었다 또한 VBC/MMA/HEMA=80/10/10의 경우 히스테리시스는 $\pm$2%RH 안에서 나타났으며, 온도의존성 계수는 -0.42~-0.46%RH/$^{\circ}C$이었다. 30%RH, 60%RH 그리고 90%RH에서의 저항 값은 각각 3.0M$\Omega$,,200k$\Omega$ 그리고 9k$\Omega$ 이었다. The copolymers with various composition of vinylbenzyl chloride (VBC), methyl methacrylate (MMA), and 2-hydroxyethyl methacrylate(HEMA) were synthesized as a humidity sensitive material and quaternized with N, N, N', N'-tetraethylene diamine.. Resistance versus relative humidity decreased with increase in the content of MMA in the copolymer. The introduction of HPMA increased the resistance of the humidity sensor as well as enhanced the adherence to the alumina substrate. In the case of VBC/MMA/HEMA=80/10/10, the hysteresis and temperature dependency coefficient were $\pm$2%RH and -0.46~0.42%RH/$^{\circ}C$. The average resistance at 30%RH, 60%RH and 90%RH were 3.0M$\Omega$ ,200k$\Omega$ and 9k$\Omega$, respectively.
메타크릴레이트계 4차 암모늄 유도체 고분자 전해질의 감습특
김태미,공명선,이임열,박정기,Kim, Tae-Mi,Gong, Myeong-Seon,Lee, Im-Yeol,Park, Jeong-Gi 한국재료학회 1993 한국재료학회지 Vol.3 No.6
고분자 전해질의 화학구조가 감습특성에 미치는 효과를 조사하기 위하여 $C_{1}\sim C_{12}$의 알킬,benzy1, 2,2-diethoxy dthy1기가 치환된 메타크릴계 4차 암모늄 단량체들을 합성하였다. 이들의 감습용액을 0.15mm간격의 빗살 모양의 금전극이 인쇄된 알루미나 기판에 마이크로 주사기로 도포하여 광중합 후 상대습도에 따른 임피던스 변화를 측정하였다. 도포된 막의 두께가 증가하면 임피던스는 감소하고, 치환기의 탄소 길이가 증가할수록 임피던스는 증가하였다. $C_6\sim C_8$의 알킬기를 가지는 고분자 전해질의 감습특성은 30-90% RH 범위에서 18M$\Omega$-5K$\Omega$의 직선적인 임피던스 변화를 보였다. 또한 임피던스는 온도 의존성을 보여주며 온도가 증가하면 임피던스가 감소하며 온도 의존성 계수는 -0,45% $RH/^{\circ}C$이다. 히스테리시스는 $\pm$2%RH이내이며, 33%-85% RH 사이에서의 응답 속도는 약 35sec이었다. Methacryloxyethyl dimethyl alkyl($C_{1}\sim C_{12}$, benzyl and 2, 2-diethoxy ethyl) ammonium bromide monomers were prepared to investigate the relative humidity characteristics for polymer electrolytes with different chemical structures. They were coated on the alumna substrate printed comblike gold electrode by photopolymerization after micro-syringe injection. As the thickness of rhe humid membrane increased, the impendance decreased, whereas the impedance ~ncreased as the carbon cham of alkyl substituent in the monomer increased. The impendance of the polymeric electrolytes with $C_6\sim C_8$ substituents were varied from 19M$\Omega$ to 5K$\Omega$ for the range of 30-90% Mi. The temperature depedence coefficient in the range of 15-$35^{\circ}C$ was found to be -0.45% $RH/^{\circ}C$and the hysteresis falled within the range of $\pm$2% RH. The response time was 35 second for varying humldity from 33% to 85% RH.
Preparation and Thermal Properties of Enaryloxynitriles End-Capped Polymer Precursors
길대수,공명선,Gil, Dae Su,Gong, Myeong Seon Korean Chemical Society 2000 Bulletin of the Korean Chemical Society Vol.21 No.6
Various enaryloxynitriles-terminated reactive polymer precursors containing rigid aromatic units were prepared from various diamines and 1-(p-formylphenyl)-1-phenyl-2,2-dicyanoethene (1). Arylate end-capped model compounds linked with azomethine bond were also prepared by reacting p-formylphenyl benzoate with diamines to compare the curing ability. The oligomers were highly soluble in polar aprotic solvents such as N,N-dimethylformamide, dimethylsulfoxide and N-methyl-2 -pyrrolidinone. They generally showed an exothermic curing process between $280-350^{\circ}C$, attributable to the thermal crosslinking of the dicyanovinyl group in DSC analysis, and no weight loss at curing temperature. Upon heating the polymer precursors, heat-resistant and insoluble network polymers were obtained. Thermogravimetric analyses of the precursors containing rigid aromatic units showed thermal stability with a 77-92% residual weight at $500^{\circ}C$ under nitrogen.
금네리,공명선,Geum, Ne Ri,Gong, Myeong Seon Korean Chemical Society 2000 Bulletin of the Korean Chemical Society Vol.21 No.11
The kinetic study of the enaryloxynitriles via the nucleophilic vinylic substitution reaction of various phenol derivatives with 1-chloro-1-phenyl-2,2-dicyanoethene (1) was conducted in the presence of 1,4-diazabicyclo[2,2,2]octane (DABCO). Nucleo philic vinylic substitution of phenol derivatives with electrophilic olefins carrying sluggish leaving group involves a third-order reaction. The reaction was applied to solution polymerization of diphenol derivatives with p-bis(1-chrolo-2,2-dicyanovinyl)benzene (2), which yielded various polyenaryloxynitriles with moderate molecular weight.
Chemiluminescence Properties of Polymeric Fluorophores Containing Distyrylarylene Unit
이희우,김철희,공명선,Lee, Hui U,Kim, Cheol Hui,Gong, Myeong Seon Korean Chemical Society 2001 Bulletin of the Korean Chemical Society Vol.22 No.7
Conjugated-non-conjugated alternating block copolymers containing distyrylarylene units were synthesized via Wittig reaction for chemiluminescent fluorophores. The polymers were differentiated from others by the presence of aromatic unit in the chromophoric block. When UV-VIS, photoluminescence and chemiluminescence spectra of these materials were compared with copolymers, a strong bathochromic effect was observed. A more pronounced red shift and higher chemiluminscence efficiency were observed in the polymer with anthracene ring. Sodium salicylate-catalyzed reaction of bis(2-carbopentyloxy-3,5,6-trichlorophenyl) oxalate with hydrogen peroxide produced a strong chemiluminescence from blue to yellow-green light emission with wavelength of 450-537 nm in the presence of the fluorophore. The chemiluminescent intensity decayed exponentially. The glow of chemiluminescence maintained more than l2 hr and was visible with the naked eye.
김진석,배장순,공명선,Kim, Jin-Seok,Bae, Jang-Sun,Gong, Myeong-Seon 한국재료학회 2001 한국재료학회지 Vol.11 No.2
4 차 암모늄염을 형성할 수 있는 공중합체들 poly[(vinylbenzyl chloride)-co-(n-butyl acrylate)-co-(2-hydroxyethyl methacrylate)]와 poly[(4-vinylpyridine)-co-(n-butyl acrylate)-co-(2-hydroxyethyl methacrylate)]를 고분자막 습도센서의 감습재료로 사용하기 위하여 합성하였다. 습도센서는 30%RH, 60%RH 그리고 90%RH에서 평균 저항 값은 각각 8.6 M $\Omega$, 310 k$\Omega$ 그리고 12 k$\Omega$을 보여 주었다. 또한 히스테리시스는 $\pm$3%RH 안에서 나타났으며, 온도의존성 계수는 -0.37~-0.407RH/$^{\circ}C$이었다. 감습막의 조성에서 공중합체 중 n-BA와 HEMA의 도입은 저항을 증가시키는 요인이 되나 기판과의 접착성은 크게 향상되었다. 33%RH에서 85%RH로 또는 역으로 변화할 때의 응답속도는 54초이며 수중에 2시간 침적 후 저항의 변화는 +0.2%RH 이내에서 존재하였다. The mutually reactive copolymers poly[(vinylbenzyl chloride)-co-(n-butyl acrylate)-co-(2-hydroxyethyl methacrylate)] and poly[(4-vinylpyridine)-co-(n-butyl acrylate)-co-(2-hydroxyethyl methacrylate)] were synthesized for the humidity sensitive material by forming simultaneous quaternization. The humidity sensor showed an average resistance of 8.6 M$\Omega$, 310 k$\Omega$ and 12 k$\Omega$ at 30%RH, 60%RH and 90%RH, respectively. The hysteresis and temperature coefficient were $\pm$3%RH and -0.37~-0.40%RH/$^{\circ}C$. The introduction of n-BA and HEMA increased the resistance of the humidity sensor however it enhanced the adherence to the alumina substrate. The response time was 54 seconds changing from 33%RH to 85%RH and the difference of resistance was +0.2%RH after soaking in water for 2 hr.