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A study for Humidity Sensor using The Charcteristics of Sensing moisture Polyvinyl alcohol is a common hydrophilic polymer but shows a significant impedance response with changing relative humidity only above 60% RH. Fabricating simply a polyvinyl alcohol film as humidity sensor lacks durability and also shows high impedance. To overcome this problem, cross-linking of polyvinyl alcohol was done with 4-styrene sulfonate (sodium salt) in presence of ferrous ions. The best results as a humidity sensor material were obtained when polyvinyl alcohol was cross-linked with 4-styrene sulfonate in presence of ferrous ions at a temperature of 140℃ for about 1 h and when polyvinyl alcohol, 4-styrene sulfonate (sodium salt hydrate) and FeCl_2·4H_2O were taken in a weight ratio of 10:2:3 respectively. The structure of the polymeric material was established using NMR and infra-red spectroscopy, to be a co-polymeric material in presence of ferrous ions. The polymeric mixture of the three materials made in water was casted on an alumina substrate (size 7.5mm×7.2mm×0.38mm) prefabricated with interdigitated gold electrodes and was cured at a temperature of 140℃. The results demonstrate that the logarithm of the resistance decreased linearly with increase in %RH in a range of 30-92% RH. Other factors viz. stability, sensitivity and response time for the fabricated sensor were also determined, * Polyvinyl alcohol (PVA) is a cheap and common hydrophilic polymer but lacks durability against moisture and shows high impedance. In this paper, several PVA based humidity sensors cross-linking it with m-benzenedisulphonate sodium salt (MBDS) in presence of various electrolytes were prepared. However, cross-linking PVA with MBDS in presence of ferrous ions showed the maximum sensitivity against relative humidity. Best results were obtained when cross-linking was done by curing the film on an alumina substrate, printed with gold electrodes at 150-160℃ and in a weight ratio of 25:5:9 for PVA : MBDS : FeCl_2·4H_2O composition. Dependence of resistance on the relative humidity(RH) showed linearity between 35 to 85%RH. Other factors viz. temperature dependence, response time were also measured. The humidity sensitive characteristice of the sensor did not change even after soaking in water for 100 min.