Diethylaniline and benzidine, the nitrogen containing organic chemicals, decomposed by supercritical water oxidation. The experiments were performed at temperature range between 380℃ and 448℃ in batch reactor. Oxygen was used as oxidant. Reaction ...
Diethylaniline and benzidine, the nitrogen containing organic chemicals, decomposed by supercritical water oxidation. The experiments were performed at temperature range between 380℃ and 448℃ in batch reactor. Oxygen was used as oxidant. Reaction orders for each reactants were determined by differential method. Activation energy and frequency factor were obtained by SAS SLIN procedure. The rate equations obtained were as follows.
Rate equation for diethylaniline:
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Rate equation for benzidine:
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