Visual colorimetric detection of ammonia under gaseous and aqueous state: Approach on cesium lead bromide perovskite-loaded porous electrospun nanofibers

다국어 초록 (Multilingual Abstract)

In this work, we fabricate porous cesium lead bromide nanofibers (CsPbBr3 NFs) via electrospinning andemploy them in a sensor to effectively detect both gaseous and aqueous ammonia. The CsPbBr3 NFs areproduced byfirst mixing cesium lead bromide nanocrystals (CsPbBr3 NCs) with polystyrene (PS),followed by solidifying the mixture into NFs using electrospinning. Porous NFs are modified using thevolatile solvent toluene, which is volatilized during the electrospinning process. The applicability of theproposed CsPbBr3 NFs for use under various environmental conditions is verified by analyzing theirstability in response to changes in temperature, moisture level and pH, which are critical drawbacks ofCsPbBr3 NCs. Gaseous ammonia (9 mg L 1) in an N2 carrier is subsequently detected using thephotoluminescence (PL) properties of the CsPbBr3 NFs. In addition, an ammonia concentration of 100.0mg L 1 in an aqueous solution can be detected using the PL intensity. Therefore, we believe that theproposed CsPbBr3 NFs show significant promise for use in detection sensors to assess the extent of fooddecay, allowing customers to purchase fresh agricultural products more safely.

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