요-드와 치오황산의 반응속도에 관한 연구 = Kinetic studies on the Reaction Rate of Iodine with Thiosulfate

다국어 초록 (Multilingual Abstract)

The reaction of iodine with thiosulfate in aqueous solution(PH=4.0) has been studied kinetically. The following mechanism is consistent with the experimental results.
◁화학식 삽입▷ (원문을 참고하세요)
◁화학식 삽입▷ (원문을 참고하세요)
◁화학식 삽입▷ (원문을 참고하세요)
At high thiosulfate ion and iodide ion concentration than the stoichiomet concentration of iodine, the rate constants of k´₁,k₁,k´₁/k₂,k´_(-1)/k₂ were determined. The rate constants in 0.1M NaClO₄ and 1×10^(-4)M HClO₄ for k₁, k´₁, k´₁/k₂, k´_(-1)/k₂were obtained as 4.55×10⁴M^(-1)·Sec^(-1), 3.74×10₄M^(-1)·Sec^(-1), 8.758×10^(-2)M^(-1), 2.391×10^(-4), respectively.

목차 (Table of Contents)

• Abstract
• I. 서론
• II. 실험
• III. 결과 및 고찰
• IV. 결론
• V. References