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      KCI등재 SCOPUS SCIE

      Effects of annealing temperature on GO-Cu2O composite films grown by electrochemical deposition for PEC photoelectrode

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      https://www.riss.kr/link?id=A104218251

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      다국어 초록 (Multilingual Abstract)

      In this work, graphene oxideecuprous oxide (GO-Cu2O) composite films were grown on fluorine-doped tin oxide substrates by electrochemical deposition. We investigated the effects of the annealing temperature on the morphological, structural, optical an...

      In this work, graphene oxideecuprous oxide (GO-Cu2O) composite films were grown on fluorine-doped tin oxide substrates by electrochemical deposition. We investigated the effects of the annealing temperature on the morphological, structural, optical and photoelectrochemical (PEC) properties of GO -Cu2O composite films. As a result, our work shows that while GO-Cu2O composite films exhibit the highest XRD (111) peak intensity at 300 ℃ sample, the highest photocurrent density value obtained was -4.75 mA/cm2 at 200 ℃ sample (using 0.17 V versus a reversible hydrogen electrode (RHE)). In addition, a reduction reaction at 300 ℃ sample was observed using XPS analysis from the shift in the O1s peak in addition to a weaker O1s peak intensity.

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      참고문헌 (Reference)

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      2 J. Su, "Vertically aligned WO3 nanowire arrays grown directly on transparent conducting oxide coated glass: synthesis and photoelectrochemical properties" 11 : 203-208, 2010

      3 김태금, "Vertical Growth of ZnO Nanorods on ITO Substrate by Using a Two-step-potential Electrochemical Deposition Method" 한국물리학회 63 (63): 78-82, 2013

      4 A. Paracchino, "Ultrathin films on copper (I) oxide water splitting photocathodes: a study on performance and stability" 5 : 8673-8681, 2012

      5 T. G. Kim, "The study of post annealing effect on Cu2O thin-films by electrochemical deposition for photoelectrochemical applications" 612 : 74-79, 2014

      6 Y. Liu, "The structural and optical properties of Cu2O films electrodeposited on different substrates" 20 : 44-, 2005

      7 H. Yu, "Template-free hydrothermal synthesis of CuO/Cu2O composite hollow microspheres" 19 : 4327-4334, 2007

      8 Y. Qian, "Synthesis of cuprous oxide (Cu2O) nanoparticles/graphene composite with an excellent electrocatalytic activity towards glucose" 7 : 2012

      9 J. Liu, "Self-assembling TiO2 nanorods on large graphene oxide sheets at a two-phase interface and their antirecombination in photocatalytic applications" 20 : 4175-4181, 2010

      10 T. Sreeprasad, "Reduced graphene oxideemetal/metal oxide composites: facile synthesis and application in water purification" 186 : 921-931, 2011

      1 E. Jamil, "ZnO nanowires, nanotubes, and complex hierarchical structures obtained by electrochemical deposition" 40 : 728-732, 2011

      2 J. Su, "Vertically aligned WO3 nanowire arrays grown directly on transparent conducting oxide coated glass: synthesis and photoelectrochemical properties" 11 : 203-208, 2010

      3 김태금, "Vertical Growth of ZnO Nanorods on ITO Substrate by Using a Two-step-potential Electrochemical Deposition Method" 한국물리학회 63 (63): 78-82, 2013

      4 A. Paracchino, "Ultrathin films on copper (I) oxide water splitting photocathodes: a study on performance and stability" 5 : 8673-8681, 2012

      5 T. G. Kim, "The study of post annealing effect on Cu2O thin-films by electrochemical deposition for photoelectrochemical applications" 612 : 74-79, 2014

      6 Y. Liu, "The structural and optical properties of Cu2O films electrodeposited on different substrates" 20 : 44-, 2005

      7 H. Yu, "Template-free hydrothermal synthesis of CuO/Cu2O composite hollow microspheres" 19 : 4327-4334, 2007

      8 Y. Qian, "Synthesis of cuprous oxide (Cu2O) nanoparticles/graphene composite with an excellent electrocatalytic activity towards glucose" 7 : 2012

      9 J. Liu, "Self-assembling TiO2 nanorods on large graphene oxide sheets at a two-phase interface and their antirecombination in photocatalytic applications" 20 : 4175-4181, 2010

      10 T. Sreeprasad, "Reduced graphene oxideemetal/metal oxide composites: facile synthesis and application in water purification" 186 : 921-931, 2011

      11 A. Musa, "Production of cuprous oxide, a solar cell material, by thermal oxidation and a study of its physical and electrical properties" 51 : 305-316, 1998

      12 S. Ishizuka, "Polycrystalline n-ZnO/p-Cu2O heterojunctions grown by RF-magnetron sputtering" 1 : 1067-1070, 2004

      13 C. M. McShane, "Photocurrent enhancement of n-type Cu2O electrodes achieved by controlling dendritic branching growth" 131 : 2561-2569, 2009

      14 K. Maeda, "Photocatalytic water splitting using semiconductor particles: history and recent developments" 12 : 237-268, 2011

      15 J. Katayama, "Performance of Cu2O/ZnO solarcell prepared by two-step electrodeposition" 34 : 687-692, 2004

      16 X. Bai, "Performance enhancement of ZnO photocatalyst via synergic effect of surface oxygen defect and graphene hybridization" 29 : 3097-3105, 2013

      17 S. Liu, "One-pot synthesis of CuO nanoflowerdecorated reduced graphene oxide and its application to photocatalytic degradation of dyes" 2 : 339-344, 2012

      18 X. Zhu, "Nanostructured reduced graphene oxide/Fe2O3 composite as a high-performance anode material for lithium ion batteries" 5 : 3333-3338, 2011

      19 H. Wang, "Mn3O4-graphene hybrid as a high-capacity anode material for lithium ion batteries" 132 : 13978-13980, 2010

      20 Q. Han, "Magnesium-doped zinc oxide electrochemically grown on fluorinedoped tin oxide substrate" 12 : 3677-3681, 2012

      21 G. Eda, "Large-area ultrathin films of reduced graphene oxide as a transparent and flexible electronic material" 3 : 270-274, 2008

      22 E. Thimsen, "Influence of plasmonic Au nanoparticles on the photoactivity of Fe2O3 electrodes for water splitting" 11 : 35-43, 2010

      23 T. G. Kim, "Impact of first-step potential and time on the vertical growth of ZnO nanorods on ITO substrate by two-step electrochemical deposition" 579 : 558-563, 2013

      24 A. Paracchino, "Highly active oxide photocathode for photoelectrochemical water reduction" 10 : 456-461, 2011

      25 M. A. Mahmoud, "Following charge separation on the nanoscale in Cu2OeAu nanoframe hollow nanoparticles" 11 : 3285-3289, 2011

      26 A. K. Rai, "Facile approach to synthesize CuO/reduced graphene oxide nanocomposite as anode materials for lithium-ion battery" 244 : 435-441, 2013

      27 C. Xu, "Fabrication of a grapheneecuprous oxide composite" 182 : 2486-2490, 2009

      28 S. Paek, "Enhanced cyclic performance and lithium storage capacity of SnO2/graphene nanoporous electrodes with three-dimensionally delaminated flexible structure" 9 : 72-75, 2008

      29 J. Nian, "Electrodeposited p-type Cu22 O for H2 evolution from photoelectrolysis of water under visible light illumination" 33 : 2897-2903, 2008

      30 Y. Hames, "Electrochemically grown ZnO nanorods for hybrid solar cell applications" 84 : 426-431, 2010

      31 S. Wu, "Electrochemical deposition of semiconductor oxides on reduced graphene oxide-based flexible, transparent, and conductive electrodes" 114 : 11816-11821, 2010

      32 L. Chen, "Electrochemical deposition of copper oxide nanowires for photoelectrochemical applications" 20 : 6962-6967, 2010

      33 Y. Zhou, "Electochemical deposition and micro structure of copper (Ⅰ) oxide films" 38 : 1731-1738, 1998

      34 R. P. Wijesundera, "Effects of annealing on the properties and structure of electrodeposited semiconducting CueO thin films" 244 : 4629-4642, 2007

      35 R. M. Liang, "Effect of annealing on the electrodeposited Cu2O films for photoelectrochemical hydrogen generation" 518 : 7191-7195, 2010

      36 Y. Mai, "CuO/graphene composite as anode materials for lithium-ion batteries" 56 : 2306-2311, 2011

      37 J. G. Radich, "Cu2S reduced graphene oxide composite for high-efficiency quantum dot solar cells. Overcoming the redox limitations of S2e/Sn 2e at the counter electrode" 2 : 2453-2460, 2011

      38 P. De Jongh, "Cu2O: electrodeposition and characterization" 11 : 3512-3517, 1999

      39 P. de Jongh, "Cu2O: a catalyst for the photochemical decomposition of water?" 1069-1070, 1999

      40 J. Kondo, "Cu2O as a photocatalyst for overall water splitting under visible light irradiation" 357-358, 1998

      41 T. Maruyama, "Copper oxide thin films prepared by chemical vapor deposition from copper dipivaloylmethanate" 56 : 85-92, 1998

      42 S. Tan, "Cluster coarsening in zinc oxide thin films by postgrowth annealing" 100 : 033502-, 2006

      43 Z. Zhang, "Carbon-layer-protected cuprous oxide nanowire arrays for efficient water reduction" 7 : 1709-1717, 2013

      44 I. S. Cho, "Branched TiO2 nanorods for photoelectrochemical hydrogen production" 11 : 4978-4984, 2011

      45 J. Y. Park, "Annealing Temperature Dependence on the Physicochemical Properties of Copper Oxide Thin Films" 대한화학회 32 (32): 1331-1335, 2011

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