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        TiO2 nanoparticles anchored on graphene oxide nanosheets as a highly active photocatalyst for decabromodiphenyl ether degradation

        Man Yang,Yilun Zou,Lei Ding,Yang Yu,Jinai Ma,Lei Li,Ande Fudja Rafryanto,Jing Zou,Arramel,Haitao Wang 한국탄소학회 2023 Carbon Letters Vol.33 No.5

        Decabromodiphenyl ether (BDE209) is a persistent aromatic compound widely associated with environmental pollutants. Given its persistence and possible bioaccumulation, exploring a feasible technique to eradicate BDE209 efficiently is critical for today’s environmentally sustainable societies. Herein, an advanced nanocomposite is elaborately constructed, in which a large number of titanium dioxide ( TiO2) nanoparticles are anchored uniformly on two-dimensional graphene oxide (GO) nanosheets ( TiO2/GO) via a modified Hummer’s method and subsequent solvothermal treatment to achieve efficient photocatalytic degradation BDE209. The obtained TiO2/ GO photocatalyst has excellent photocatalytic due to the intense coupling between conductive GO nanosheets and TiO2 nanoparticles. Under the optimal photocatalytic degradation test conditions, the degradation efficiency of BDE209 is more than 90%. In addition, this study also provides an efficient route for designing highly active catalytic materials.

      • KCI등재

        Solvothermal preparation of CeO2 nanoparticles–graphene nanocomposites as an electrochemical sensor for sensitive detecting pentachlorophenol

        Yang Man,Chen Yiyang,Wang Haitao,Zou Yilun,Wu Pingxiu,Zou Jing,Jiang Jizhou 한국탄소학회 2022 Carbon Letters Vol.32 No.5

        Pentachlorophenol (PCP), as one of the common pesticide and preservatives, is easily accumulated in living organisms. Considering the high toxicity of PCP, the development of an effective and sensitive inspection method to determine the residual trace amounts of PCP continues to be a significant challenge. Herein, a convenient and sensitive electrochemical sensor is constructed by modifying glassy carbon electrode with cerium dioxide (CeO2) nanoparticles anchored graphene (CeO2-GR) to detect trace PCP. Benefiting from the two-dimensional lamellar structural advantages, the extraordinary electron-transfer properties, as well as the intensive coupling effect between CeO2 nanoparticles and graphene, the afforded CeO2-GR electrode nanomaterial possesses excellent electrocatalytic activity for the oxidation of PCP. Under the optimum synthetic conditions, the PCP oxidation peak currents of developed CeO2–GR sample exhibit a wide linear range of 5–150 μM. Moreover, the corresponding detection limit of PCP on the CeO2–GR electrode is as low as 0.5 μM. Apart from providing a promising electrochemical sensor, this work, most importantly, promotes an efficient route for the construction of highly active sensing electrode materials.

      • KCI등재

        Correction to: Solvothermal preparation of CeO2 nanoparticles–graphene nanocomposites as an electrochemical sensor for sensitive detecting pentachlorophenol

        Yang Man,Chen Yiyang,Wang Haitao,Zou Yilun,Wu Pingxiu,Zou Jing,Jiang Jizhou 한국탄소학회 2022 Carbon Letters Vol.32 No.7

        Pentachlorophenol (PCP), as one of the common pesticide and preservatives, is easily accumulated in living organisms. Considering the high toxicity of PCP, the development of an effective and sensitive inspection method to determine the residual trace amounts of PCP continues to be a significant challenge. Herein, a convenient and sensitive electrochemical sensor is constructed by modifying glassy carbon electrode with cerium dioxide (CeO2) nanoparticles anchored graphene (CeO2-GR) to detect trace PCP. Benefiting from the two-dimensional lamellar structural advantages, the extraordinary electron-transfer properties, as well as the intensive coupling effect between CeO2 nanoparticles and graphene, the afforded CeO2-GR electrode nanomaterial possesses excellent electrocatalytic activity for the oxidation of PCP. Under the optimum synthetic conditions, the PCP oxidation peak currents of developed CeO2–GR sample exhibit a wide linear range of 5–150 μM. Moreover, the corresponding detection limit of PCP on the CeO2–GR electrode is as low as 0.5 μM. Apart from providing a promising electrochemical sensor, this work, most importantly, promotes an efficient route for the construction of highly active sensing electrode materials.

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