http://chineseinput.net/에서 pinyin(병음)방식으로 중국어를 변환할 수 있습니다.
변환된 중국어를 복사하여 사용하시면 됩니다.
- 中文 을 입력하시려면 zhongwen을 입력하시고 space를누르시면됩니다.
- 北京 을 입력하시려면 beijing을 입력하시고 space를 누르시면 됩니다.
RISS 인기검색어
- 검색키워드
- 저자 : Yair Kaufman (검색결과 5 건)
- 무료
- 기관 내 무료
- 유료
-
Kaufman, Yair,Chen, Szu-Ying,Mishra, Himanshu,Schrader, Alex M.,Lee, Dong Woog,Das, Saurabh,Donaldson Jr., Stephen H.,Israelachvili, Jacob N. American Chemical Society 2017 The Journal of Physical Chemistry Part C Vol.121 No.10
<P>Rough/patterned/textured surfaces with nano/microcavities that broaden below the surface known as 're-entrants'-can be omniphobic (macroscopic contact angle greater than 90 for both water and oils). The existing theoretical models that explain the effects of texture on wetting are complex and do not provide a simple procedure for predicting the thermodynamically stable and metastable states and their corresponding contact angles (for example, wetting states that involve partially filled cavities). Here, we develop a simple-to-apply wetting model that allows for (1) predicting a priori the wetting state (partially or fully filled) of the cavities both under and outside the liquid droplet and the corresponding macroscopic contact angles on any type of textured surface; (2) determining the conditions under which metastable states exist; and (3) engineering specific nano/microtextures that yield any desired macroscopic contact angle, theta(v) for a given intrinsic contact angle theta(0). Subsequently, we experimentally demonstrate how one can use the model to predict the metastable and the thermodynamically stable contact angles on nondeformable textured surfaces consisting of arrays of axisymmetric cavities/protrusions. In this model, we do not consider the effects of gravitational forces, Laplace pressure of the droplet, line tension, droplet impact velocity, and quantitative aspects of contact angle hysteresis. Nonetheless, the model is suitable for accurately predicting the contact angles of macroscopic droplets (droplet volume similar to 1 mu L and base diameters <2 mm), which is of immense relevance in engineering. In the experimental section we also discuss the suitability of the model to be extended in order to include the effects of contact angle hysteresis on the macroscopic apparent contact angle on textured surfaces. Controlling these macroscopic contact angles, whether higher or lower than the intrinsic angle, theta(0), is desirable for many applications including nonwetting, self-cleaning, and antifouling surfaces and for completely wetting/spreading applications, such as creams, cosmetics, and lubricant fluids.</P>
-
Chen, Szu-Ying,Kaufman, Yair,Schrader, Alex M.,Seo, Dongjin,Lee, Dong Woog,Page, Steven H.,Koenig, Peter H.,Isaacs, Sandra,Gizaw, Yonas,Israelachvili, Jacob N. American Chemical Society 2017 Langmuir Vol.33 No.38
<P>Measuring truly equilibrium adhesion energies or contact angles to obtain the thermodynamic values is experimentally difficult because it requires loading/unloading or advancing/receding boundaries to be measured at rates that can be slower than 1 nm/s. We have measured advancing-receding contact angles and loading-unloading adhesion energies for various systems and geometries involving molecularly smooth and chemically homogeneous surfaces moving at different but steady velocities in both directions, ±<I>V</I>, focusing on the thermodynamic limit of ±<I>V</I> → 0. We have used the Bell Theory (1978) to derive expressions for the dynamic (velocity-dependent) adhesion energies and contact angles suitable for both (i) dynamic adhesion measurements using the classic Johnson-Kendall-Roberts (JKR, 1971) theory of “contact mechanics” and (ii) dynamic contact angle hysteresis measurements of both rolling droplets and syringe-controlled (sessile) droplets on various surfaces. We present our results for systems that exhibited both steady and varying velocities from <I>V</I> ≈ 10 mm/s to 1 nm/s, where in all cases but one, the advancing (<I>V</I> > 0) and receding (<I>V</I> < 0) adhesion energies and/or contact angles converged toward the same theoretical (thermodynamic) values as <I>V</I> → 0. Our equations for the dynamic contact angles are similar to the classic equations of Blake & Haynes (1969) and fitted the experimental adhesion data equally well over the range of velocities studied, although with somewhat different fitting parameters for the characteristic molecular <I>length/dimension</I> or <I>area</I> and characteristic bond formation/rupture <I>lifetime</I> or <I>velocity</I>. Our theoretical and experimental methods and results unify previous kinetic theories of adhesion and contact angle hysteresis and offer new experimental methods for testing kinetic models in the thermodynamic, <I>quasi-static</I>, limit. Our analyses are limited to kinetic effects only, and we conclude that hydrodynamic, i.e., viscous, and inertial effects do not play a role at the interfacial velocities of our experiments, i.e., <I>V</I> < (1-10) mm/s (for water and hexadecane, but for viscous polymers it may be different), consistent with previously reported studies.</P> [FIG OMISSION]</BR>
-
Rates of cavity filling by liquids
Seo, Dongjin,Schrader, Alex M.,Chen, Szu-Ying,Kaufman, Yair,Cristiani, Thomas R.,Page, Steven H.,Koenig, Peter H.,Gizaw, Yonas,Lee, Dong Woog,Israelachvili, Jacob N. National Academy of Sciences 2018 PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF Vol.115 No.32
<P>Understanding the fundamental wetting behavior of liquids on surfaces with pores or cavities provides insights into the wetting phenomena associated with rough or patterned surfaces, such as skin and fabrics, as well as the development of everyday products such as ointments and paints, and industrial applications such as enhanced oil recovery and pitting during chemical mechanical polishing. We have studied, both experimentally and theoretically, the dynamics of the transitions from the unfilled/partially filled (Cassie-Baxter) wetting state to the fully filled (Wenzel) wetting state on intrinsically hydrophilic surfaces (intrinsic water contact angle <90 degrees, where the Wenzel state is always the thermodynamically favorable state, while a temporary metastable Cassie-Baxter state can also exist) to determine the variables that control the rates of such transitions. We prepared silicon wafers with cylindrical cavities of different geometries and immersed them in bulk water. With bright-field and confocal fluorescence microscopy, we observed the details of, and the rates associated with, water penetration into the cavities from the bulk. We find that unconnected, reentrant cavities (i.e., cavities that open up below the surface) have the slowest cavity-filling rates, while connected or non-reentrant cavities undergo very rapid transitions. Using these unconnected, reentrant cavities, we identified the variables that affect cavity-filling rates: (i) the intrinsic contact angle, (ii) the concentration of dissolved air in the bulk water phase (i.e., aeration), (iii) the liquid volatility that determines the rate of capillary condensation inside the cavities, and (iv) the presence of surfactants.</P>
-
-
연관 검색어 추천
이 검색어로 많이 본 자료
활용도 높은 자료
