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      • Retail place attachment: a qualitative study of apparel shoppers

        Katherine Shaw,Pauline Sullivan 한국마케팅과학회 2013 Journal of Global Fashion Marketing Vol.4 No.4

        This exploratory study proposes an empirical look at the meaning of place attachmentfor the retail consumer and studies its role in online shopping patronage. A theoreticalframework was developed from a review of the literature, and guides this research. Thedependent variable in this study was retail place attachment. The aim of the study wasto validate constructs of retail place attachment and identify its influence on onlineretail patronage. A total of 429 participants were randomly chosen from a social-networking databaseand two professional organization databases using the snowball sampling technique. Inclusion criteria for this sample included gender, age range of 18 and up, and all ethnicbackgrounds. Survey participants were recruited from Facebook, a social-networkingdatabase, and two professional organization databases. Identifying that consumers value both hedonic and utilitarian aspects of theirshopping experience, this study assists in understanding the meaning of the term “retailplace attachment.” Retailers should focus on increasing both the emotional and socialbond to their stores while offering quality merchandise at affordable prices.

      • EMBEDDING THE LOOP: SUSTAINING CIRCULARITIES IN CLOTHING CONSUMPTION

        Katherine Duffy,Deirdre Shaw 글로벌지식마케팅경영학회 2017 Global Fashion Management Conference Vol.2017 No.07

        Much of the sustainability research has orientated around the production side of the business model, changing a consumer’s consumption pattern, such as extending the usage of a product and reducing the frequency of purchase and even promoting shared use, is now being recognised as a critical facet of working towards sustainability. The focus on the consumer perspective, their usage and response to alternative modes of garment use is under represented in the research to-date, which has predominantly focused on the point of design or disposal. Employing a multi-method qualitative study, this research engages with consumers to build the critical insights currently pertinent but neglected in shifting consumers towards more sustainable fashion consumption practices. Fashion management is important as evidenced by a global garment industry valued at around US $1.7 trillion and employing approximately 75 million people (Fashion United; International Labour Organisation). However, there are significant environmental costs from resource inputs, manufacture, use and disposal of clothing. This impact occurs while around only 30% of clothing, valued at around ?4000, in our wardrobes was worn in the last year (Williams, 2016). Coupled with an increase in clothing purchases, this has led to the phenomena of disposing of garments that may only have been worn a few times. Disposal of clothing is a key tenet of sustainability, with high volumes of purchases propelled by discourses of “fast fashion” (Bianchi and Birtwistle, 2010) resulting in approximately one million tonnes of clothes being disposed annually in the UK (Defra, 2009). Whilst a need for consumer behaviour change is clearly identified for systemic change within fashion management, little insight is provided as to how this can be facilitated. From a production and retail perspective, sustainable clothing discussions have been appropriated into mainstream retail practice (in brands such as People Tree, Patagonia, Everlane, H&M) however one of the presented barriers of a mainstream adoption of this approach, is the lack of trust and weak incentives for consumers. With the premise of extending understandings beyond interested niche fashion groups to mainstream society, we explore tensions and opportunities in extending clothing acquisition practices towards a circular approach. Focusing on fashion consumers (considered as purchasing one fashion item per week) we carried out a multi-method ethnographic study over six months to intervene and challenge consumer fashion consumption habits. We augment the conventional model of fashion consumer behaviour of ‘buy-own-dispose’ and contribute an emergent understanding of the challenges, barriers and opportunities of sustainable clothing consumption and the implications for fashion management.

      • Uranium-Incorporated Iron (Oxyhydr) Oxide in Geodisposal Systems: The Effects of Biogeochemical Perturbations on Long-Term Stability

        Samuel Shaw,Olwen Stagg,Katherine Morris,Liam Abrahamsen-Mills,Luke Townsend,Thomas S. Niell,J. Frederick W. Mosselmans 한국방사성폐기물학회 2023 한국방사성폐기물학회 학술논문요약집 Vol.21 No.2

        In all geodisposal scenarios it is key to understand the interaction of radionuclides with mineral particles during their formation/recrystallisation. Studying processes at the molecular scale provides insight into long-term radionuclide behaviour. Uranium is a significant radionuclide in higher activity wastes destined for geological disposal, and iron (oxyhydr) oxides (e.g. goethite, ?-FeOOH). are ubiquitous in and around these systems, formed via processes including metal corrosion and microbially induced reactions. There are numerous reports of uranium-incorporation into iron (oxyhydr) oxides, therefore it has been suggested that they may be a barrier to uranium migration in geodisposal systems. However, long-term stability of these phases during environmental perturbations are unexplored. Specifically, U-incorporated iron (oxyhydr) oxide phases may interact with Fe(II) and sulphide from biological or geological origin. Firstly, electron transfer occurs between adsorbed Fe(II) and iron oxyhydroxides, with potential for changes in the speciation of incorporated uranium e.g. oxidation state changes and/or release. Secondly, on exposure to aqueous sulfide, iron (oxyhydr) oxides undergo reductive dissolution and recrystallisation to iron sulphides. Understanding the fate of incorporated uranium during these process in key to understanding its long term behaviour in subsurface systems. A series of experimental studies were undertaken where U(VI)-goethite was synthesized then reacted with either aqueous Fe(II) or S(-II), and the system monitored over time using geochemical analysis and X-ray absorption spectroscopy (XAS) techniques e.g. U LIII-edge and MIV-edge HERFD-XANES. Reaction with aqueous Fe(II) resulted in electron transfer between Fe(II) and U(VI)-goethite, with > 50% U(VI) reduced to U(V). XAS analysis revealed that U remained within the goethite structure, and electron transfer only occurred within the outermost atomic layers of goethite. which led to U reduction. Rapid reductive dissolution of U(VI)-goethite occurred on reaction with sulfide at pH7. A transient release of aqueous U was observed during the first day, likely due to uranyl(VI)-persulfide species. However, U was retained in the solid phase in the longer term. In contrast, the sulfidation of U adsorbed to ferrihydrite at pH 12.2 led to the immediate release of U (< 10% Utotal) associated with a colloidal erdite (NaFeS2·2H2O) phase. Moreover, in the bulk phase the surface of ferrihydrite was passivated by sulfide, and U was found to have been trapped within surface associated erdite-like fibres. Overall, these studies further understanding of the long-term behaviour of U-incorporated iron (oxyhydr)oxides supporting the overarching concept of iron (oxyhydr) oxides acting as a barrier to U migration.

      • KCI등재

        Bioremediation Options for Nuclear Sites a Review of an Emerging Technology

        Callum Robinson,Matthew White-Pettigrew,Samuel Shaw,Katherine Morris,James Graham,Jonathan R. Lloyd 한국방사성폐기물학회 2022 방사성폐기물학회지 Vol.20 No.3

        60+ Years of nuclear power generation has led to a significant legacy of radioactively contaminated land at a number of nuclear licenced “mega sites” around the world. The safe management and remediation of these sites is key to ensuring there environmental stewardship in the long term. Bioremediation utilizes a variety of microbially mediated processes such as, enzymatically driven metal reduction or biominerialisation, to sequester radioactive contaminants from the subsurface limiting their migration through the geosphere. Additionally, some of these process can provide environmentally stable sinks for radioactive contaminants, through formation of highly insoluble mineral phases such as calcium phosphates and carbonates, which can incorporate a range of radionuclides into their structure. Bioremediation options have been considered and deployed in preference to conventional remediation techniques at a number of nuclear “mega” sites. Here, we review the applications of bioremediation technologies at three key nuclear licenced sites; Rifle and Hanford, USA and Sellafield, UK, in the remediation of radioactively contaminated land.

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