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Preparation and Characterization of Ultramicroporous Carbons for Hydrogen Storage
이슬이(Lee, Seul-Yi),박수진(Park, Soo-Jin) 한국신재생에너지학회 2011 한국신재생에너지학회 학술대회논문집 Vol.2011 No.05
In this work, we prepared ultramicroporous carbons (UC) prepared by pyrolyzing poly(vinylidene fluoride) with different carbonization temperatures, and investigated the hydrogen storage behaviors. The surface functional groups and specific elements of UC were confirmed by Fourier-transform infrared spectroscopy (FT-IR) and X-ray photoelectron spectroscopy (XPS), respectively. Textural properties were analyzed using N₂ adsorption isotherms at 77 K. The hydrogen storage capacity of the UC samples were investigated by BEL-HP at 298 K/10 MPa. From the results, it was found that the hydrogen storage capacity was enhanced with increasing of specific surface area, resulting from the formation of ultramicropore on the UC.
Effect of Magnesium Nanoparticles on Graphite Oxide for Hydrogen Storage Behaviors
이슬이(Lee, Seul-Yi),박수진(Park, Soo-Jin) 한국신재생에너지학회 2011 한국신재생에너지학회 학술대회논문집 Vol.2011 No.05
In this work, we prepared Mg nanoparticles loaded graphite oxide (Mg-G) as a function of Mg content in order to investigate hydrogen storage behaviors. The structure and morphology of the Mg-G samples were characterized by X-ray diffraction (XRD) and field emission scanning electron microscopy (FE-SEM). The textural properties of the samples were evaluated using N₂/77 K adsorption isotherms. The hydrogen adsorption capacities were investigated at 298 K/10 MPa. As a result, the hydrogen adsorption capacities of the Mg-G were enhanced with increasing the Mg content. Therefore, it was found that the presence of Mg on graphite surfaces created hydrogen-favorable sites, resulting in enhancing the hydrogen adsorption capacity.
Effect of Nickel Oxide on Hydrogen Storage Behaviors of Mesoporous SBA-15
이슬이(Lee, Seul-Yi),박수진(Park, Soo-Jin) 한국신재생에너지학회 2009 한국신재생에너지학회 학술대회논문집 Vol.2009 No.11
In this work, we prepared the Ni-loaded porous SBA-15 (SBA-15) by a depositionprecipitation (D-P) method, in order to enhance the hydrogen storage capacity. The structure and morphology of the Ni/SBA-15 were characterized by X-ray diffraction (XRD) and field emission transmission electron microscopy (FE-TEM). The results showed that, at the Ni loading used at the DP times in the range of 0-120 min, SBA-15 preserved the well-ordered hexagonal porous arrangement. The textural properties of the Ni/SBA-15 were analyzed using N2 adsorption isotherms at 77 K. Specific surface area and mesopore volume of the samples were determined from the Brunauer-Emmett-Teller (BET) equation and Barrett-Joiner-Halenda (BJH) method, respectively. The hydrogen storage capacity of the Ni/SBA-15 was evaluated at 298 K/10 MPa. The hydrogen storage capacity of the Ni/SBA-15 was increased in accordance with Ni content. Consequently, it was found that the presence of Ni on mesoporous SBA-15 created hydrogen-favorable sites which enhanced the hydrogen storage capacity by spillover effect.