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김민채 ( Min Chae Kim ),박민의 ( Min Ui Park ),박노일 ( No Il Park ),이슬비 ( Seul Bi Lee ),이성민 ( Seong Min Lee ),양소연 ( So Yeon Yang ),최종혁 ( Jong Hyuk Choi ),정대원 ( Dae-won Chung ) 한국공업화학회 2016 공업화학 Vol.27 No.1
In the presence of poly(4-styrene sulfonate) (PSS) and excess amount of graphene oxide (GO), we conducted in-situ polymerization of 3,4-ethylenedioxythiophene (EDOT) without an oxidant. XPS and IR spectroscopies of the product (GO-P) showed that PEDOT/PSS was successfully synthesized by oxidative polymerization of EDOT and hybridized with GO. GO-P displayed a stable aqueous suspension, however, the high content (42%) of GO in GO-P diminished electrical conductivity down to 15 S·m-1. Annealing of GO-P films at 200 ℃ for 8 hr induced partial reduction of GO and finally enhanced electrical conductivity up to 212 S·m-1.